New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)

The Burela deposit is the largest kaolin deposit in Spain, mined for more than 50 years, the product being mainly used for porcelain. Kaolin is dominantly associated with Lower Cambrian felsites, interbedded with quartzites, micaschists and metapelites (Cándana Series), and was strongly folded durin...

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Autores: Galán Huertos, Emilio, Aparicio Fernández, Patricia, Fernández Caliani, Juan Carlos, Miras Ruiz, Adolfo, Márquez González, Marcial Gabino, Fallick, Anthony E., Clauer, Norbert
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Recursos:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/152699
Acesso em linha:https://hdl.handle.net/11441/152699
https://doi.org/10.1016/j.clay.2015.11.015
Access Level:acceso abierto
Palavra-chave:Galicia
Halloysite
Isotopes
Kaolin genesis
Spain
Trace elements
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spelling New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)Galán Huertos, EmilioAparicio Fernández, PatriciaFernández Caliani, Juan CarlosMiras Ruiz, AdolfoMárquez González, Marcial GabinoFallick, Anthony E.Clauer, NorbertGaliciaHalloysiteIsotopesKaolin genesisSpainTrace elementsThe Burela deposit is the largest kaolin deposit in Spain, mined for more than 50 years, the product being mainly used for porcelain. Kaolin is dominantly associated with Lower Cambrian felsites, interbedded with quartzites, micaschists and metapelites (Cándana Series), and was strongly folded during the Variscan orogeny. Kaolin layers were ductile and incompetent materials among more competent ones, producing many slides with a diastrophic appearance. Consequently, kaolin outcrops are morphologically very variable– i.e. pockets – and interlayered between metapelites and/or quartzites, resulting in complication for prospection and mining. The kaolin consists mainly of kaolinite, tubular halloysite, and spherical allophane along with quartz and minor illite. The content of kaolin minerals reaches up to 90% in the finer fractions (< 2 μm and < 1 μm). Geochemical analyses of trace and REE show a close relationship between kaolin and associated rocks. Two kaolin types can be differentiated: (i) massive, associated to felsite; and (ii) related to metapelite. A temperature range from 15 to 35 °C, with an average of approximately 28 °C was calculated on the basis of the isotopic signatures (δ18O, δD) for the kaolin materials. This scatter suggests that if continental weathering was involved in the kaolin formation on the lower side of the temperatures, it was not the only process, especially for kaolin associate with felsites and metapelites. The higher temperatures are indicative of a hydrothermal auto-metamorphic alteration, followed by a folding of the series that induced an apparently chaotic kaolin distribution with a combined continental weathering superimposed on the previous low-temperature hydrothermal felsite transformation.Ministerio de Educación y Ciencia BET2001-2415Junta de Andalucía RNM135ElsevierCristalografía, Mineralogía y Química AgrícolaMinisterio de Educación y Ciencia (MEC). EspañaJunta de Andalucía2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/152699https://doi.org/10.1016/j.clay.2015.11.015reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésApplied Clay Science, 131, 14-26.BET2001-2415RNM135https://doi.org/10.1016/j.clay.2015.11.015info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1526992026-06-17T12:51:07Z
dc.title.none.fl_str_mv New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
title New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
spellingShingle New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
Galán Huertos, Emilio
Galicia
Halloysite
Isotopes
Kaolin genesis
Spain
Trace elements
title_short New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
title_full New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
title_fullStr New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
title_full_unstemmed New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
title_sort New insights on mineralogy and genesis of kaolin deposits: The Burela kaolin deposit (Northwestern Spain)
dc.creator.none.fl_str_mv Galán Huertos, Emilio
Aparicio Fernández, Patricia
Fernández Caliani, Juan Carlos
Miras Ruiz, Adolfo
Márquez González, Marcial Gabino
Fallick, Anthony E.
Clauer, Norbert
author Galán Huertos, Emilio
author_facet Galán Huertos, Emilio
Aparicio Fernández, Patricia
Fernández Caliani, Juan Carlos
Miras Ruiz, Adolfo
Márquez González, Marcial Gabino
Fallick, Anthony E.
Clauer, Norbert
author_role author
author2 Aparicio Fernández, Patricia
Fernández Caliani, Juan Carlos
Miras Ruiz, Adolfo
Márquez González, Marcial Gabino
Fallick, Anthony E.
Clauer, Norbert
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Cristalografía, Mineralogía y Química Agrícola
Ministerio de Educación y Ciencia (MEC). España
Junta de Andalucía
dc.subject.none.fl_str_mv Galicia
Halloysite
Isotopes
Kaolin genesis
Spain
Trace elements
topic Galicia
Halloysite
Isotopes
Kaolin genesis
Spain
Trace elements
description The Burela deposit is the largest kaolin deposit in Spain, mined for more than 50 years, the product being mainly used for porcelain. Kaolin is dominantly associated with Lower Cambrian felsites, interbedded with quartzites, micaschists and metapelites (Cándana Series), and was strongly folded during the Variscan orogeny. Kaolin layers were ductile and incompetent materials among more competent ones, producing many slides with a diastrophic appearance. Consequently, kaolin outcrops are morphologically very variable– i.e. pockets – and interlayered between metapelites and/or quartzites, resulting in complication for prospection and mining. The kaolin consists mainly of kaolinite, tubular halloysite, and spherical allophane along with quartz and minor illite. The content of kaolin minerals reaches up to 90% in the finer fractions (< 2 μm and < 1 μm). Geochemical analyses of trace and REE show a close relationship between kaolin and associated rocks. Two kaolin types can be differentiated: (i) massive, associated to felsite; and (ii) related to metapelite. A temperature range from 15 to 35 °C, with an average of approximately 28 °C was calculated on the basis of the isotopic signatures (δ18O, δD) for the kaolin materials. This scatter suggests that if continental weathering was involved in the kaolin formation on the lower side of the temperatures, it was not the only process, especially for kaolin associate with felsites and metapelites. The higher temperatures are indicative of a hydrothermal auto-metamorphic alteration, followed by a folding of the series that induced an apparently chaotic kaolin distribution with a combined continental weathering superimposed on the previous low-temperature hydrothermal felsite transformation.
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/152699
https://doi.org/10.1016/j.clay.2015.11.015
url https://hdl.handle.net/11441/152699
https://doi.org/10.1016/j.clay.2015.11.015
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Applied Clay Science, 131, 14-26.
BET2001-2415
RNM135
https://doi.org/10.1016/j.clay.2015.11.015
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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