Anomalous behaviour of pentane adsorbed at the graphite/liquid interface

Calorimetry and neutron di†raction have been used to identify and characterise the formation of a solid monolayer of pentane adsorbed on graphite and coexisting with liquid pentane. The observed behaviour is quite di†erent from other alkanes in that the monolayer does not melt above the melting temp...

Descripción completa

Detalles Bibliográficos
Autores: Castro Arroyo, Miguel Ángel, Clarke, Stuart M., Inaba, Akira, Arnold, Thomas, Thomas, Robert K.
Tipo de recurso: artículo
Fecha de publicación:1999
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/23349
Acceso en línea:http://hdl.handle.net/11441/23349
Access Level:acceso abierto
id ES_4e30df5d02f9c024aa6489ee866bd7ce
oai_identifier_str oai:idus.us.es:11441/23349
network_acronym_str ES
network_name_str España
repository_id_str
spelling Anomalous behaviour of pentane adsorbed at the graphite/liquid interfaceCastro Arroyo, Miguel ÁngelClarke, Stuart M.Inaba, AkiraArnold, ThomasThomas, Robert K.Calorimetry and neutron di†raction have been used to identify and characterise the formation of a solid monolayer of pentane adsorbed on graphite and coexisting with liquid pentane. The observed behaviour is quite di†erent from other alkanes in that the monolayer does not melt above the melting temperature of the pure pentane but at a temperature very similar to that of the bulk material. The lower melting point of the bulk pentane in the pentane/graphite system, when it is present in a relatively small amount, allows the melting point of the solid monolayer to be clearly resolved.Química Inorgánica1999info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttp://hdl.handle.net/11441/23349reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésPhysical Chemistry Chemical Physics: PCCP, 1, 5203-520710.1039/A905597Einfo:eu-repo/semantics/openAccessoai:idus.us.es:11441/233492026-06-17T12:51:07Z
dc.title.none.fl_str_mv Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
title Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
spellingShingle Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
Castro Arroyo, Miguel Ángel
title_short Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
title_full Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
title_fullStr Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
title_full_unstemmed Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
title_sort Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
dc.creator.none.fl_str_mv Castro Arroyo, Miguel Ángel
Clarke, Stuart M.
Inaba, Akira
Arnold, Thomas
Thomas, Robert K.
author Castro Arroyo, Miguel Ángel
author_facet Castro Arroyo, Miguel Ángel
Clarke, Stuart M.
Inaba, Akira
Arnold, Thomas
Thomas, Robert K.
author_role author
author2 Clarke, Stuart M.
Inaba, Akira
Arnold, Thomas
Thomas, Robert K.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Química Inorgánica
description Calorimetry and neutron di†raction have been used to identify and characterise the formation of a solid monolayer of pentane adsorbed on graphite and coexisting with liquid pentane. The observed behaviour is quite di†erent from other alkanes in that the monolayer does not melt above the melting temperature of the pure pentane but at a temperature very similar to that of the bulk material. The lower melting point of the bulk pentane in the pentane/graphite system, when it is present in a relatively small amount, allows the melting point of the solid monolayer to be clearly resolved.
publishDate 1999
dc.date.none.fl_str_mv 1999
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/11441/23349
url http://hdl.handle.net/11441/23349
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Physical Chemistry Chemical Physics: PCCP, 1, 5203-5207
10.1039/A905597E
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869407740189736960
score 15.301603

Similares en LA Referencia