Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets

We present the synthesis and structural characterization of the salt [Fe(bpp)2][MnCr(ox)3]2 · bpp · CH3OH. It crystallizes in the monoclinic space group. This material contains an anionic [MnCr(ox)3]− 3D 10-gon ferromagnetic network, that orders below 3.0 K. The channels created by this architecture...

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Authors: Coronado, Eugenio, Galán Mascarós, José R., Giménez López, María del Carmen, Almeida, Manuel, Waerenborgh, João Carlos
Format: article
Publication Date:2006
Country:España
Institution:Universidad de Santiago de Compostela (USC)
Repository:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Language:English
OAI Identifier:oai:minerva.usc.gal:10347/32319
Online Access:http://hdl.handle.net/10347/32319
Access Level:Open access
Keyword:230307 Compuestos de coordinación
220208 Magnetismo
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spelling Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnetsCoronado, EugenioGalán Mascarós, José R.Giménez López, María del CarmenAlmeida, ManuelWaerenborgh, João Carlos230307 Compuestos de coordinación220208 MagnetismoWe present the synthesis and structural characterization of the salt [Fe(bpp)2][MnCr(ox)3]2 · bpp · CH3OH. It crystallizes in the monoclinic space group. This material contains an anionic [MnCr(ox)3]− 3D 10-gon ferromagnetic network, that orders below 3.0 K. The channels created by this architecture are filled by the spin crossover cations [Fe(bpp)2]2+ (bpp = 2,6(bispyrazol-3-yl)pyridine), free ligand and solvent molecules. No spin transition has been observed at ambient pressure.ElsevierUniversidade de Santiago de Compostela. Departamento de Química Inorgánica20062006-01-0120062006-01-01journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10347/32319reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostelainstname:Universidad de Santiago de Compostela (USC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2CC BY-NC-ND 4.0http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:minerva.usc.gal:10347/323192026-06-15T12:47:27Z
dc.title.none.fl_str_mv Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
title Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
spellingShingle Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
Coronado, Eugenio
230307 Compuestos de coordinación
220208 Magnetismo
title_short Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
title_full Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
title_fullStr Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
title_full_unstemmed Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
title_sort Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
dc.creator.none.fl_str_mv Coronado, Eugenio
Galán Mascarós, José R.
Giménez López, María del Carmen
Almeida, Manuel
Waerenborgh, João Carlos
author Coronado, Eugenio
author_facet Coronado, Eugenio
Galán Mascarós, José R.
Giménez López, María del Carmen
Almeida, Manuel
Waerenborgh, João Carlos
author_role author
author2 Galán Mascarós, José R.
Giménez López, María del Carmen
Almeida, Manuel
Waerenborgh, João Carlos
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade de Santiago de Compostela. Departamento de Química Inorgánica
dc.subject.none.fl_str_mv 230307 Compuestos de coordinación
220208 Magnetismo
topic 230307 Compuestos de coordinación
220208 Magnetismo
description We present the synthesis and structural characterization of the salt [Fe(bpp)2][MnCr(ox)3]2 · bpp · CH3OH. It crystallizes in the monoclinic space group. This material contains an anionic [MnCr(ox)3]− 3D 10-gon ferromagnetic network, that orders below 3.0 K. The channels created by this architecture are filled by the spin crossover cations [Fe(bpp)2]2+ (bpp = 2,6(bispyrazol-3-yl)pyridine), free ligand and solvent molecules. No spin transition has been observed at ambient pressure.
publishDate 2006
dc.date.none.fl_str_mv 2006
2006-01-01
2006
2006-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10347/32319
url http://hdl.handle.net/10347/32319
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
CC BY-NC-ND 4.0
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
CC BY-NC-ND 4.0
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
instname:Universidad de Santiago de Compostela (USC)
instname_str Universidad de Santiago de Compostela (USC)
reponame_str Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
collection Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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