Viability of bauxite deposits from Catalonia (Spain) for ceramic applications

<p>This study provides a characterization of materials from wastes and outcrops of twoinactive bauxite mines located close to Sant Joan de Mediona and Peramola, Spain. Mineralogy wasdetermined via powder X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR).Thermal propert...

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Detalles Bibliográficos
Autores: Martinez, Arnau, Garcia Vallès, Maite, Alfonso Abella, María Pura
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/206400
Acceso en línea:https://hdl.handle.net/2445/206400
Access Level:acceso abierto
Palabra clave:Bauxita
Mineralogia
Jaciments minerals
Catalunya
Materials ceràmics
Bauxite
Mineralogy
Mineral deposits
Catalonia
Ceramic materials
Descripción
Sumario:<p>This study provides a characterization of materials from wastes and outcrops of twoinactive bauxite mines located close to Sant Joan de Mediona and Peramola, Spain. Mineralogy wasdetermined via powder X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR).Thermal properties were measured via differential thermal analysis–thermogravimetry (DTA-TG) andgresification tests. The crystalline phases are medium-high crystalline kaolinite and variable amountsof illite, quartz, calcite, boehmite, hematite and rutile/anatase. DTA show two endothermic peaksproduced by the dehydroxylation of minerals: the first peak, at 530–538 C, belongs to boehmite; thesecond peak, at 535–568 C, corresponds to kaolinite. An exothermic peak at 950–978 C is associatedwith mullite crystallization. The optimal sintering temperatures obtained from the gresification curves(firing shrinkage and water absorption) were 970 C for carbonate-poor, illite-rich clays; 1100 C forillite- and carbonate-poor samples; and near 1190 C for carbonate-rich materials. The carbonate-poorsamples fired at 1300 C contain sillimanite and mullite, and the carbonate-rich materials are richin gehlenite, anorthite, and hedenbergite. The mineralogy of these materials is sufficient to obtainceramic materials with suitable properties, but not their low plasticity. They could be used in theformulation of bricks or as part of mixtures to produce refractory ceramics.</p>