COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption

Synergistic effects between porous materials offer a powerful route to enhance key functionalities such as adsorption, catalysis, and molecular transport. In this context, the combination of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) provides a promising platform for engi...

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Autores: Guillem-Navajas, Ana, Torrico-García-Viso, Lucía, Suárez del Pino, José Antonio, Aramburu-Merino, Nekane, Segovia Cabrero, María Pilar, García Michel, Enrique, Puigmartí-Luis, Josep, Velasco Caravaca, Enrique, Tarazona Lafarga, Pedro José, Maspoch, Daniel
Tipo de recurso: artículo
Fecha de publicación:2025
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/738420
Acceso en línea:https://hdl.handle.net/10486/738420
https://dx.doi.org/10.1002/adma.202514548
Access Level:acceso abierto
Palabra clave:covalent organic frameworks
interphases
metal–organic frameworks
nanocomposites
synergistic molecular adsorption
water adsorption
Química
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spelling COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorptionGuillem-Navajas, AnaTorrico-García-Viso, LucíaSuárez del Pino, José AntonioAramburu-Merino, NekaneSegovia Cabrero, María PilarGarcía Michel, EnriquePuigmartí-Luis, JosepVelasco Caravaca, EnriqueTarazona Lafarga, Pedro JoséMaspoch, Danielcovalent organic frameworksinterphasesmetal–organic frameworksnanocompositessynergistic molecular adsorptionwater adsorptionQuímicaSynergistic effects between porous materials offer a powerful route to enhance key functionalities such as adsorption, catalysis, and molecular transport. In this context, the combination of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) provides a promising platform for engineering hybrid adsorbents with synergistic sorption behavior. Here, a versatile layer-by-layer strategy is presented for the controlled growth of crystalline COF shells on MOF nanoparticles, yielding uniform MOF@COF nanocomposites as stable aqueous colloids. This approach enables precise tuning of shell thickness and porosity under mild conditions. The resulting core–shell hybrids exhibit enhanced water adsorption, driven by the formation with the intrinsic micropores of the COF shell of interfacial mesopores. Modeling studies indicate that a minimum number of COF growth cycles is necessary to induce these mesopores, which nterconnect and facilitate synergistic uptake. This work presents a scalable and modular approach to creating porous hybrid nanoparticles with programmable interfacial architectures and enhanced sorption performanceFinancial support from the Spanish Ministry of Science and Innovation, through the Grant Nos. TED02021-129886B-C42, TED02021-129886BC44, PID2022-138908NB-C31 and through the “María de Maeztu” Programme for Units of Excellence in R&D CEX2023-001316-M. The authors acknowledge support from the European Innovation Council under Grant AgreementNo. 101047081 (EVA). The authors also acknowledge the support from the “(MAD2D-CM)-UAM” and TEC-2024/ECO-332 projects funded by Comunidad de Madrid, by the Recovery, Transformation, and Resilience Plan, and by NextGenerationEU from the European Union. This work has also been funded by the Catalan AGAUR (Project No. 2021 SGR 00458), and the CERCA Programme/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa Centres of Excellence program, Grant No. CEX2021-001214-S, funded by MCIN/AEI/10.13039.501100011033WileyDepartamento de Química InorgánicaDepartamento de Física de la Materia CondensadaFacultad de CienciasGobierno de España20252025-11-19research articlehttp://purl.org/coar/resource_type/c_2df8fbb1VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10486/738420https://dx.doi.org/10.1002/adma.202514548reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/7384202026-06-23T12:46:27Z
dc.title.none.fl_str_mv COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
title COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
spellingShingle COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
Guillem-Navajas, Ana
covalent organic frameworks
interphases
metal–organic frameworks
nanocomposites
synergistic molecular adsorption
water adsorption
Química
title_short COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
title_full COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
title_fullStr COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
title_full_unstemmed COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
title_sort COFs on MOFs: Layer-by-layer synthesis of MOF@COF nanoparticles with synergistic adsorption
dc.creator.none.fl_str_mv Guillem-Navajas, Ana
Torrico-García-Viso, Lucía
Suárez del Pino, José Antonio
Aramburu-Merino, Nekane
Segovia Cabrero, María Pilar
García Michel, Enrique
Puigmartí-Luis, Josep
Velasco Caravaca, Enrique
Tarazona Lafarga, Pedro José
Maspoch, Daniel
author Guillem-Navajas, Ana
author_facet Guillem-Navajas, Ana
Torrico-García-Viso, Lucía
Suárez del Pino, José Antonio
Aramburu-Merino, Nekane
Segovia Cabrero, María Pilar
García Michel, Enrique
Puigmartí-Luis, Josep
Velasco Caravaca, Enrique
Tarazona Lafarga, Pedro José
Maspoch, Daniel
author_role author
author2 Torrico-García-Viso, Lucía
Suárez del Pino, José Antonio
Aramburu-Merino, Nekane
Segovia Cabrero, María Pilar
García Michel, Enrique
Puigmartí-Luis, Josep
Velasco Caravaca, Enrique
Tarazona Lafarga, Pedro José
Maspoch, Daniel
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Química Inorgánica
Departamento de Física de la Materia Condensada
Facultad de Ciencias
Gobierno de España
dc.subject.none.fl_str_mv covalent organic frameworks
interphases
metal–organic frameworks
nanocomposites
synergistic molecular adsorption
water adsorption
Química
topic covalent organic frameworks
interphases
metal–organic frameworks
nanocomposites
synergistic molecular adsorption
water adsorption
Química
description Synergistic effects between porous materials offer a powerful route to enhance key functionalities such as adsorption, catalysis, and molecular transport. In this context, the combination of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) provides a promising platform for engineering hybrid adsorbents with synergistic sorption behavior. Here, a versatile layer-by-layer strategy is presented for the controlled growth of crystalline COF shells on MOF nanoparticles, yielding uniform MOF@COF nanocomposites as stable aqueous colloids. This approach enables precise tuning of shell thickness and porosity under mild conditions. The resulting core–shell hybrids exhibit enhanced water adsorption, driven by the formation with the intrinsic micropores of the COF shell of interfacial mesopores. Modeling studies indicate that a minimum number of COF growth cycles is necessary to induce these mesopores, which nterconnect and facilitate synergistic uptake. This work presents a scalable and modular approach to creating porous hybrid nanoparticles with programmable interfacial architectures and enhanced sorption performance
publishDate 2025
dc.date.none.fl_str_mv 2025
2025-11-19
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10486/738420
https://dx.doi.org/10.1002/adma.202514548
url https://hdl.handle.net/10486/738420
https://dx.doi.org/10.1002/adma.202514548
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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