Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks

Conditions were established for the separation and analysis of Bisphenol A (BPA), Bisphenol F (BPF), and their diglycidyl ethers, by micellar electrokinetic capillary chromatography (MECC). Good resolution was obtained for all compounds, although in order to achieve the separation of ortho-ortho, or...

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Autores: Gallart Ayala, Hèctor, Núñez Burcio, Oscar, Moyano Morcillo, Encarnación, Galcerán Huguet, M. Teresa
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2010
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/98193
Acceso en línea:https://hdl.handle.net/2445/98193
Access Level:acceso abierto
Palabra clave:Begudes carbòniques
Química dels aliments
Fenols
Cromatografia
Envasament d'aliments
Carbonated beverages
Food composition
Phenols
Chromatography
Food packaging
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spelling Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinksGallart Ayala, HèctorNúñez Burcio, OscarMoyano Morcillo, EncarnaciónGalcerán Huguet, M. TeresaBegudes carbòniquesQuímica dels alimentsFenolsCromatografiaEnvasament d'alimentsCarbonated beveragesFood compositionPhenolsChromatographyFood packagingConditions were established for the separation and analysis of Bisphenol A (BPA), Bisphenol F (BPF), and their diglycidyl ethers, by micellar electrokinetic capillary chromatography (MECC). Good resolution was obtained for all compounds, although in order to achieve the separation of ortho-ortho, ortho-para, and para-para isomers of Bisphenol F diglycidyl ether (BFDGE), BFDGE¿2H2O and BFDGE¿2HCl, it was necessary to use a 25 µm I.D. fused-silica capillary. To increase sensitivity, a field amplified sample injection (FASI)-MECC method was developed using 10 mM sodium dodecyl sulfate (SDS) solution as injection matrix and a 75 µm I.D. fused-silica capillary. Instrumental quality parameters such as limits of detection (0.999), and run-to-run and day-to-day precisions (relative standard deviations (RSD) values lower than 12.5%) were determined. Finally, the suitability of the FASI-MECC method for the analysis of BPA, BPF and their diglycidyl ethers in canned soft-drinks was evaluated. Quantitation was performed by matrix-matched calibration using a plastic-bottled isotonic drink as matrix. The results showed that FASI-MECC is an economic method for the screening and quantitation of these kinds of compounds in soft-drink beverages, with no loss of reproducibility, and effective at concentrations lower than the specific migration level (SML) values established by the European Union.Wiley-VCH2010info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2445/98193Articles publicats en revistes (Enginyeria Química i Química Analítica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésVersió postprint del document publicat a: http://dx.doi.org/10.1002/elps.200900606Electrophoresis, 2010, vol. 31, num. 9, p. 1550-1559http://dx.doi.org/10.1002/elps.200900606(c) Wiley-VCH, 2010info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/981932026-05-27T06:46:51Z
dc.title.none.fl_str_mv Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
title Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
spellingShingle Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
Gallart Ayala, Hèctor
Begudes carbòniques
Química dels aliments
Fenols
Cromatografia
Envasament d'aliments
Carbonated beverages
Food composition
Phenols
Chromatography
Food packaging
title_short Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
title_full Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
title_fullStr Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
title_full_unstemmed Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
title_sort Field-amplified sample injection-micellar electrokinetic capillary chromatography for the analysis of bisphenol A, bisphenol F, and their diglycidyl ethers and derivatives in canned soft drinks
dc.creator.none.fl_str_mv Gallart Ayala, Hèctor
Núñez Burcio, Oscar
Moyano Morcillo, Encarnación
Galcerán Huguet, M. Teresa
author Gallart Ayala, Hèctor
author_facet Gallart Ayala, Hèctor
Núñez Burcio, Oscar
Moyano Morcillo, Encarnación
Galcerán Huguet, M. Teresa
author_role author
author2 Núñez Burcio, Oscar
Moyano Morcillo, Encarnación
Galcerán Huguet, M. Teresa
author2_role author
author
author
dc.subject.none.fl_str_mv Begudes carbòniques
Química dels aliments
Fenols
Cromatografia
Envasament d'aliments
Carbonated beverages
Food composition
Phenols
Chromatography
Food packaging
topic Begudes carbòniques
Química dels aliments
Fenols
Cromatografia
Envasament d'aliments
Carbonated beverages
Food composition
Phenols
Chromatography
Food packaging
description Conditions were established for the separation and analysis of Bisphenol A (BPA), Bisphenol F (BPF), and their diglycidyl ethers, by micellar electrokinetic capillary chromatography (MECC). Good resolution was obtained for all compounds, although in order to achieve the separation of ortho-ortho, ortho-para, and para-para isomers of Bisphenol F diglycidyl ether (BFDGE), BFDGE¿2H2O and BFDGE¿2HCl, it was necessary to use a 25 µm I.D. fused-silica capillary. To increase sensitivity, a field amplified sample injection (FASI)-MECC method was developed using 10 mM sodium dodecyl sulfate (SDS) solution as injection matrix and a 75 µm I.D. fused-silica capillary. Instrumental quality parameters such as limits of detection (0.999), and run-to-run and day-to-day precisions (relative standard deviations (RSD) values lower than 12.5%) were determined. Finally, the suitability of the FASI-MECC method for the analysis of BPA, BPF and their diglycidyl ethers in canned soft-drinks was evaluated. Quantitation was performed by matrix-matched calibration using a plastic-bottled isotonic drink as matrix. The results showed that FASI-MECC is an economic method for the screening and quantitation of these kinds of compounds in soft-drink beverages, with no loss of reproducibility, and effective at concentrations lower than the specific migration level (SML) values established by the European Union.
publishDate 2010
dc.date.none.fl_str_mv 2010
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/98193
url https://hdl.handle.net/2445/98193
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: http://dx.doi.org/10.1002/elps.200900606
Electrophoresis, 2010, vol. 31, num. 9, p. 1550-1559
http://dx.doi.org/10.1002/elps.200900606
dc.rights.none.fl_str_mv (c) Wiley-VCH, 2010
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) Wiley-VCH, 2010
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv Articles publicats en revistes (Enginyeria Química i Química Analítica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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