High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid

[EN] This work reports the development of poly(lactic acid) (PLA) formulations with improved toughness by ternary blends with poly(3-hydroxybutyrate) (PHB) and two different flexible polyesters derived from succinic acid, namely poly(butylene succinate) (PBS) and a copolymer, poly(butylene succinate...

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Autores: GARCÍA CAMPO, MARÍA JESÚS, Quiles-Carrillo, Luis|||0000-0001-8037-2215, Sanchez-Nacher, Lourdes|||0000-0002-8627-4576, Balart, Rafael|||0000-0001-5670-7126, Montanes, Nestor|||0000-0001-6070-127X
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/126495
Acceso en línea:https://riunet.upv.es/handle/10251/126495
Access Level:acceso abierto
Palabra clave:Poly(lactic acid) (PLA)
Impact toughness
Ternary blends
Mechanical properties
Morphology
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
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spelling High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acidGARCÍA CAMPO, MARÍA JESÚSQuiles-Carrillo, Luis|||0000-0001-8037-2215Sanchez-Nacher, Lourdes|||0000-0002-8627-4576Balart, Rafael|||0000-0001-5670-7126Montanes, Nestor|||0000-0001-6070-127XPoly(lactic acid) (PLA)Impact toughnessTernary blendsMechanical propertiesMorphologyCIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA[EN] This work reports the development of poly(lactic acid) (PLA) formulations with improved toughness by ternary blends with poly(3-hydroxybutyrate) (PHB) and two different flexible polyesters derived from succinic acid, namely poly(butylene succinate) (PBS) and a copolymer, poly(butylene succinate-co-adipate) (PBSA). The main aim of this work is to increase the low intrinsic toughness of PLA without compromising the thermal properties by manufacturing ternary blends using epoxidized vegetable oils as compatibilizer agents. The ternary blends were manufactured by reactive extrusion in a co-rotating extruder and were subjected to mechanical, thermal, thermos-mechanical and morphology characterization. The obtained results confirm that these two succinic acid-derived polymers, i.e., PBS and PBSA, positively contribute to increase ductile properties in ternary blends with PLA and PHB with a subsequent improvement on impact toughness. In addition, both epoxidized vegetable oils, ELO and ESBO, are responsible for somewhat compatibilization between all three polyesters in blends which gives improved ductile properties with regard to uncompatibilized ternary blends. In addition, the temperature range in which these materials can be used is broader than ternary blends with other flexible polyester such as poly(e-caprolactone), as both PBS and PBSA melt at about 100 °C. These PLA-based materials with improved impact properties offer interesting applications in the packaging industry.This work was supported by the Ministry of Economy and Competitiveness (MINECO) Grant Numbers MAT2014-59242-C2-1-R and MAT2017-84909-C2-2-R. L. Quiles-Carrillo acknowledges Generalitat Valenciana (GV) for financial support through a FPI Grant (ACIF/2016/182) and the Spanish Ministry of Education, Culture, and Sports (MECD) for his FPU Grant (FPU15/03812).Springer-VerlagDepartamento de Matemática AplicadaDepartamento de Ingeniería Mecánica y de Materiales Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyGeneralitat ValencianaMinisterio de EducaciónAgencia Estatal de InvestigaciónMinisterio de Economía, Industria y CompetitividadRepositorio Institucional de la Universitat Politècnica de València Riunet20182018-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/126495reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2014-59242-C2-1-R TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOSAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 MAT2017-84909-C2-2-R PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOSGeneralitat Valenciana https://doi.org/10.13039/501100003359 ACIF%2F2016%2F182Ministerio de Educación y Cultura http://dx.doi.org/10.13039/501100003176 FPU15%2F03812 FPU15%2F03812open accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1264952026-06-13T07:49:27Z
dc.title.none.fl_str_mv High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
title High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
spellingShingle High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
GARCÍA CAMPO, MARÍA JESÚS
Poly(lactic acid) (PLA)
Impact toughness
Ternary blends
Mechanical properties
Morphology
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
title_short High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
title_full High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
title_fullStr High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
title_full_unstemmed High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
title_sort High toughness poly (lactic acid) (PLA) formulations obtained by ternary blends with poly (3-hydroxybutyrate) (PHB) and flexible polyesters from succinic acid
dc.creator.none.fl_str_mv GARCÍA CAMPO, MARÍA JESÚS
Quiles-Carrillo, Luis|||0000-0001-8037-2215
Sanchez-Nacher, Lourdes|||0000-0002-8627-4576
Balart, Rafael|||0000-0001-5670-7126
Montanes, Nestor|||0000-0001-6070-127X
author GARCÍA CAMPO, MARÍA JESÚS
author_facet GARCÍA CAMPO, MARÍA JESÚS
Quiles-Carrillo, Luis|||0000-0001-8037-2215
Sanchez-Nacher, Lourdes|||0000-0002-8627-4576
Balart, Rafael|||0000-0001-5670-7126
Montanes, Nestor|||0000-0001-6070-127X
author_role author
author2 Quiles-Carrillo, Luis|||0000-0001-8037-2215
Sanchez-Nacher, Lourdes|||0000-0002-8627-4576
Balart, Rafael|||0000-0001-5670-7126
Montanes, Nestor|||0000-0001-6070-127X
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Matemática Aplicada
Departamento de Ingeniería Mecánica y de Materiales
 Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV
Escuela Politécnica Superior de Alcoy
Generalitat Valenciana
Ministerio de Educación
Agencia Estatal de Investigación
Ministerio de Economía, Industria y Competitividad
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Poly(lactic acid) (PLA)
Impact toughness
Ternary blends
Mechanical properties
Morphology
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
topic Poly(lactic acid) (PLA)
Impact toughness
Ternary blends
Mechanical properties
Morphology
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
description [EN] This work reports the development of poly(lactic acid) (PLA) formulations with improved toughness by ternary blends with poly(3-hydroxybutyrate) (PHB) and two different flexible polyesters derived from succinic acid, namely poly(butylene succinate) (PBS) and a copolymer, poly(butylene succinate-co-adipate) (PBSA). The main aim of this work is to increase the low intrinsic toughness of PLA without compromising the thermal properties by manufacturing ternary blends using epoxidized vegetable oils as compatibilizer agents. The ternary blends were manufactured by reactive extrusion in a co-rotating extruder and were subjected to mechanical, thermal, thermos-mechanical and morphology characterization. The obtained results confirm that these two succinic acid-derived polymers, i.e., PBS and PBSA, positively contribute to increase ductile properties in ternary blends with PLA and PHB with a subsequent improvement on impact toughness. In addition, both epoxidized vegetable oils, ELO and ESBO, are responsible for somewhat compatibilization between all three polyesters in blends which gives improved ductile properties with regard to uncompatibilized ternary blends. In addition, the temperature range in which these materials can be used is broader than ternary blends with other flexible polyester such as poly(e-caprolactone), as both PBS and PBSA melt at about 100 °C. These PLA-based materials with improved impact properties offer interesting applications in the packaging industry.
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/126495
url https://riunet.upv.es/handle/10251/126495
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2014-59242-C2-1-R TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOS
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 MAT2017-84909-C2-2-R PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS
Generalitat Valenciana https://doi.org/10.13039/501100003359 ACIF%2F2016%2F182
Ministerio de Educación y Cultura http://dx.doi.org/10.13039/501100003176 FPU15%2F03812 FPU15%2F03812
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer-Verlag
publisher.none.fl_str_mv Springer-Verlag
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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