Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer

Unformatted post-print version of the accepted article

Bibliographic Details
Authors: Wang, Zefan, Dong, Xia, Cavallo, Dario, Wang, Dujin, Müller Sánchez, Alejandro Jesús
Format: article
Publication Date:2021
Country:España
Institution:Universidad del País Vasco
Repository:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/60039
Online Access:http://hdl.handle.net/10810/60039
Access Level:Open access
Keyword:polybutene-1
self-nucleation
melt memory
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spelling Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymerWang, ZefanDong, XiaCavallo, DarioWang, DujinMüller Sánchez, Alejandro Jesúspolybutene-1self-nucleationmelt memoryUnformatted post-print version of the accepted articleThe self-nucleation behavior of a polybutene-1/ethylene random copolymer, P(B1-ran-E), which undergoes a complex crystal-crystal transition behavior, has been studied in detail. Similar to PE random copolymers, this material shows a strong melt memory effect even above equilibrium melting point of PB-1 homopolymer. Different polymorphic forms can be obtained when P(B1-ran-E) is cooled from different self-nucleation Domains. The trigonal form I' could only be nucleated in the presence of remaining form I crystals via self-seeding, while the melt memory in Domain IIa could only act as self-nuclei for kinetically favored form II. Furthermore, observations from optical microscopy illustrated that melt memory is able to enhance nucleation density but it does not affect the spherulitic growth rate.Financial supports from the National Science Foundation of China (Grant No. U1510207) and the Key Program for Coal-based Science and Technology of Shanxi Province (MH-2014-08) are gratefully acknowledged. We would like to acknowledge the financial support from the BIODEST project, this project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 778092. AJM would also like to acknowledge funding from the Basque Government through grant IT1309-19.WileyEuropean Commission202320232021info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10810/60039reponame:Addi. Archivo Digital para la Docencia y la Investigacióninstname:Universidad del País VascoInglésinfo:eu-repo/grantAgreement/EC/H2020/778092https://onlinelibrary.wiley.com/doi/10.1002/pcr2.10201info:eu-repo/semantics/openAccess© 2021 Wiley Periodicals LLC.oai:addi.ehu.eus:10810/600392026-06-18T09:23:17Z
dc.title.none.fl_str_mv Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
title Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
spellingShingle Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
Wang, Zefan
polybutene-1
self-nucleation
melt memory
title_short Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
title_full Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
title_fullStr Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
title_full_unstemmed Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
title_sort Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer
dc.creator.none.fl_str_mv Wang, Zefan
Dong, Xia
Cavallo, Dario
Wang, Dujin
Müller Sánchez, Alejandro Jesús
author Wang, Zefan
author_facet Wang, Zefan
Dong, Xia
Cavallo, Dario
Wang, Dujin
Müller Sánchez, Alejandro Jesús
author_role author
author2 Dong, Xia
Cavallo, Dario
Wang, Dujin
Müller Sánchez, Alejandro Jesús
author2_role author
author
author
author
dc.contributor.none.fl_str_mv European Commission
dc.subject.none.fl_str_mv polybutene-1
self-nucleation
melt memory
topic polybutene-1
self-nucleation
melt memory
description Unformatted post-print version of the accepted article
publishDate 2021
dc.date.none.fl_str_mv 2021
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10810/60039
url http://hdl.handle.net/10810/60039
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/EC/H2020/778092
https://onlinelibrary.wiley.com/doi/10.1002/pcr2.10201
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
© 2021 Wiley Periodicals LLC.
eu_rights_str_mv openAccess
rights_invalid_str_mv © 2021 Wiley Periodicals LLC.
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:Addi. Archivo Digital para la Docencia y la Investigación
instname:Universidad del País Vasco
instname_str Universidad del País Vasco
reponame_str Addi. Archivo Digital para la Docencia y la Investigación
collection Addi. Archivo Digital para la Docencia y la Investigación
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869407463282835456
score 15,300724

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