Life cycle assessment of hydrogen and power production by supercritical water reforming of glycerol
The environmental performance of hydrogen and electricity production by supercritical water reforming (SCWR) of glycerol was evaluated following a Life Cycle Assessment (LCA) approach. The heat-integrated process was designed to be energy self-sufficient. Mass and energy balances needed for the stud...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/172058 |
| Acceso en línea: | https://hdl.handle.net/11441/172058 https://doi.org/10.1016/j.enconman.2015.03.031 |
| Access Level: | acceso abierto |
| Palabra clave: | Life cycle assessment Supercritical water Glycerol Hydrogen production Reforming Environmental impact |
| Sumario: | The environmental performance of hydrogen and electricity production by supercritical water reforming (SCWR) of glycerol was evaluated following a Life Cycle Assessment (LCA) approach. The heat-integrated process was designed to be energy self-sufficient. Mass and energy balances needed for the study were performed using Aspen Plus 8.4, and the environmental assessment was carried out through SimaPro 8.0. CML 2000 was selected as the life cycle impact assessment method, considering as impact categories the global warming, ozone layer depletion, abiotic depletion, photochemical oxidant formation, eutrophication, acidification, and cumulative energy demand. A distinction between biogenic and fossil CO2 emissions was done to quantify a more realistic GHG inventory of 3.77 kg CO2-eq per kg H2 produced. Additionally, the environmental profile of SCWR process was compared to other H2 production technologies such as steam methane reforming, carbon gasification, water electrolysis and dark fermentation among others. This way, it is shown that SCWR of glycerol allows reducing greenhouse gas emissions and obtaining a favorable positive life cycle energy balance, achieving a good environmental performance of H2 and power production by SCWR of glycerol. |
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