Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides
This is the peer reviewed version of the following article: Isotta, E. [et al.]. Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides. "ADVANCED FUNCTIONAL MATERIALS", 20 Maig 2022, núm. 2202157, which has been published in final form at https...
| Autores: | , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/369719 |
| Acceso en línea: | https://hdl.handle.net/2117/369719 https://dx.doi.org/10.1002/adfm.202202157 |
| Access Level: | acceso abierto |
| Palabra clave: | Thermoelectricity Al-doped ZnO (AZO) Kesterite CZTS CZTSe Thermoelectric generators Thin films Termoelectricitat Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica |
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Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides |
| title |
Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides |
| spellingShingle |
Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides Isotta, Eleonora Thermoelectricity Al-doped ZnO (AZO) Kesterite CZTS CZTSe Thermoelectric generators Thermoelectricity Thin films Termoelectricitat Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica |
| title_short |
Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides |
| title_full |
Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides |
| title_fullStr |
Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides |
| title_full_unstemmed |
Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides |
| title_sort |
Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides |
| dc.creator.none.fl_str_mv |
Isotta, Eleonora Andrade Arvizu, Jacob Syafiq, Ubaidah Jiménez Arguijo, Alex|||0000-0002-3583-0958 Navarro Güell, Alejandro Guc, Maxim|||0000-0002-2072-9566 Saucedo Silva, Edgardo Ademar|||0000-0003-2123-6162 Scardi, Paolo |
| author |
Isotta, Eleonora |
| author_facet |
Isotta, Eleonora Andrade Arvizu, Jacob Syafiq, Ubaidah Jiménez Arguijo, Alex|||0000-0002-3583-0958 Navarro Güell, Alejandro Guc, Maxim|||0000-0002-2072-9566 Saucedo Silva, Edgardo Ademar|||0000-0003-2123-6162 Scardi, Paolo |
| author_role |
author |
| author2 |
Andrade Arvizu, Jacob Syafiq, Ubaidah Jiménez Arguijo, Alex|||0000-0002-3583-0958 Navarro Güell, Alejandro Guc, Maxim|||0000-0002-2072-9566 Saucedo Silva, Edgardo Ademar|||0000-0003-2123-6162 Scardi, Paolo |
| author2_role |
author author author author author author author |
| dc.subject.none.fl_str_mv |
Thermoelectricity Al-doped ZnO (AZO) Kesterite CZTS CZTSe Thermoelectric generators Thermoelectricity Thin films Termoelectricitat Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica |
| topic |
Thermoelectricity Al-doped ZnO (AZO) Kesterite CZTS CZTSe Thermoelectric generators Thermoelectricity Thin films Termoelectricitat Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica |
| description |
This is the peer reviewed version of the following article: Isotta, E. [et al.]. Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides. "ADVANCED FUNCTIONAL MATERIALS", 20 Maig 2022, núm. 2202157, which has been published in final form at https://onlinelibrary.wiley.com/doi/10.1002/adfm.202202157. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. |
| publishDate |
2022 |
| dc.date.none.fl_str_mv |
2022 2022-05-20 2022 2022-07-06 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 VoR http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/article |
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article |
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https://hdl.handle.net/2117/369719 https://dx.doi.org/10.1002/adfm.202202157 |
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https://hdl.handle.net/2117/369719 https://dx.doi.org/10.1002/adfm.202202157 |
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Inglés eng |
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Inglés |
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eng |
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Agencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-116719RB-C41 DESARROLLO DE COMPUESTOS MIXTOS CALCOGENUROS-HALUROS DE BAJA DIMENSION POR RUTAS FISICAS PARA APLICACIONES EN DISPOSITIVOS FOTOVOLTAICOS TANDEM |
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open access http://purl.org/coar/access_right/c_abf2 Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/ |
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info:eu-repo/semantics/openAccess |
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open access http://purl.org/coar/access_right/c_abf2 Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/ |
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openAccess |
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application/pdf |
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reponame:UPCommons. Portal del coneixement obert de la UPC instname:Universitat Politècnica de Catalunya (UPC) |
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UPCommons. Portal del coneixement obert de la UPC |
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Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenidesIsotta, EleonoraAndrade Arvizu, JacobSyafiq, UbaidahJiménez Arguijo, Alex|||0000-0002-3583-0958Navarro Güell, AlejandroGuc, Maxim|||0000-0002-2072-9566Saucedo Silva, Edgardo Ademar|||0000-0003-2123-6162Scardi, PaoloThermoelectricityAl-doped ZnO (AZO)Kesterite CZTS CZTSeThermoelectric generatorsThermoelectricityThin filmsTermoelectricitatÀrees temàtiques de la UPC::Energies::Energia solar fotovoltaicaThis is the peer reviewed version of the following article: Isotta, E. [et al.]. Towards low cost and sustainable thin film thermoelectric devices based on quaternary chalcogenides. "ADVANCED FUNCTIONAL MATERIALS", 20 Maig 2022, núm. 2202157, which has been published in final form at https://onlinelibrary.wiley.com/doi/10.1002/adfm.202202157. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.A major challenge in thermoelectrics (TEs) is developing devices made of sustainable, abundant, and non-toxic materials. Furthermore, the technological drive toward low sizes makes crucial the study of nano and micro configurations. In this work, thin film TE devices based on p-type Cu2+xZn1-xSnS4 and Cu2+xZn1-xSnSe4, and n-type AlyZn1-yO are fabricated by physical vapor deposition. The kesterite phases show good purity and promising TE power factor, likely enhanced by the copper–zinc order–disorder transition. Thin film generators in planar configuration are assembled by a sequential deposition of the p-type, n-type, and contact materials. The power per unit planar area reaches 153 and 279 nW cm-2 for the sulphur- and selenium-based generators, respectively. These values significantly outperform any other literature attempt based on sustainable and low-cost thin films. Furthermore, if compared with traditional TEs often made of scarce and toxic materials, these devices offer a cost reduction above 80%. This allows reaching comparable values of power density per unit material cost, representing a first real step toward the development of sustainable and non-toxic thin film TE devices. These can find applications in micro energy harvesters, microelectronics coolers, and temperature controllers for wearables, medical appliances, and sensors for the internet of things.A.J. thanks the European Social Fund+ for the FI fellowship. The authors would like to acknowledge the help of Dr. Mirco D’Incau, Dr. Narges Ataollahi, and Prof. Della Volpe for the design of the measuring setup, as well as useful discussion with Prof. Dario Narducci. This research has received funding from the Spanish Ministry of Science, Innovation and Universities under the MATER-ONE projects (PID2020-116719RB-C41). Authors from IREC belong to the SEMS (Solar Energy Materials and Systems) Consolidated Research Group of the “Generalitat de Catalunya” (ref. 2017 SGR 862) and are grateful to European Regional Development Funds (ERDF, FEDER Programa Competitivitat de Catalunya 2007–2013). M.G. acknowledges the financial support from Spanish Ministry of Science, Innovation and Universities within the Juan de la Cierva fellowship (IJC2018-038199-I). E.S. acknowledges the ICREA Academia Program. Open Access Funding provided by Universita degli Studi di Trento within the CRUI-CARE Agreement.Peer Reviewed20222022-05-2020222022-07-06journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/369719https://dx.doi.org/10.1002/adfm.202202157reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)InglésengAgencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-116719RB-C41 DESARROLLO DE COMPUESTOS MIXTOS CALCOGENUROS-HALUROS DE BAJA DIMENSION POR RUTAS FISICAS PARA APLICACIONES EN DISPOSITIVOS FOTOVOLTAICOS TANDEMopen accesshttp://purl.org/coar/access_right/c_abf2Attribution 4.0 Internationalhttps://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/3697192026-05-27T15:37:01Z |
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15.300719 |