Vibrational and 57Fe-Mössbauer spectra of LaFeGe 2O7 and NdFeGe2O7

The infrared, Raman and 57Fe-Mössbauer spectra of LaFeGe2O7 and NdFeGe2O7 were recorded and analysed on the basis of their structural characteristics. Some comparisons with the stoichiometrically related materials containing the heavier lanthanides are made, showing that it is possible to differenti...

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Detalhes bibliográficos
Autores: Baran, E. J., Mercader, R. C., Cascales, Concepción
Formato: artículo
Fecha de publicación:2004
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/412799
Acesso em linha:http://hdl.handle.net/10261/412799
https://api.elsevier.com/content/abstract/scopus_id/4944249036
Access Level:acceso abierto
Palavra-chave:A. Inorganic compounds
C. Infrared spectroscopy
C. Mössbauer spectroscopy
C. Raman spectroscopy
Descrição
Resumo:The infrared, Raman and 57Fe-Mössbauer spectra of LaFeGe2O7 and NdFeGe2O7 were recorded and analysed on the basis of their structural characteristics. Some comparisons with the stoichiometrically related materials containing the heavier lanthanides are made, showing that it is possible to differentiate spectroscopically both groups of materials. The Mössbauer parameters clearly reflect the small structural differences in the FeO5-polyhedra present in these compounds.