Recent advances in the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides

Catalytic asymmetric 1,3-dipolar cycloadditions of azomethine ylides have turned out to be one of the most efficient methods for the preparation of enantioenriched pyrrolidines. The past decade has witnessed the development of a bunch of well-defined catalytic systems capable of affording excellent...

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Detalles Bibliográficos
Autores: Adrio Sevilla, Francisco Javier, Carretero Gonzálvez, Juan Carlos
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/670700
Acceso en línea:http://hdl.handle.net/10486/670700
https://dx.doi.org/10.1039/C4CC04381B
Access Level:acceso abierto
Palabra clave:Aldehyde
Azomethine ylide
Carbonyl derivative
Fluorine
Fullerene derivative
Pyrrolidine derivative
Quinone derivative
Thiourea
Química
Descripción
Sumario:Catalytic asymmetric 1,3-dipolar cycloadditions of azomethine ylides have turned out to be one of the most efficient methods for the preparation of enantioenriched pyrrolidines. The past decade has witnessed the development of a bunch of well-defined catalytic systems capable of affording excellent diastereo and enantioselectivities. Recently, a great effort has been focused on expanding the scope of the cycloaddition with regard to both reaction partners. In this review, we will discuss important advances that have been reported in this area since 2011