Cellulose nanocrystals reinforced environmentally-friendly waterborne polyurethane nanocomposites
Focusing on eco-friendly materials, cellulose nanocrystals (CNC) have gained attention as nanoreinforcement due to their exceptional properties conferred by the elevated length/diameter aspect ratio and high specific mechanical properties. Furthermore, their water dispersibility makes them suitable...
| Autores: | , , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Recursos: | Universidad del País Vasco |
| Repositorio: | Addi. Archivo Digital para la Docencia y la Investigación |
| OAI Identifier: | oai:addi.ehu.eus:10810/64845 |
| Acesso em linha: | http://hdl.handle.net/10810/64845 |
| Access Level: | acceso abierto |
| Palavra-chave: | waterborne polyurethane cellulose nanocrystals nanocomposites mechanical properties thermomechanical stability |
| Resumo: | Focusing on eco-friendly materials, cellulose nanocrystals (CNC) have gained attention as nanoreinforcement due to their exceptional properties conferred by the elevated length/diameter aspect ratio and high specific mechanical properties. Furthermore, their water dispersibility makes them suitable nanoreinforcements for their incorporation in waterborne polyurethanes (WBPU). The possibility of tailoring the properties by varying the composition and nature of the reagents, opens the opportunity for a wide range of applications. Therefore, in this work a WBPU was synthesized for the preparation of nanocomposite films with different CNC content and the properties of the films were analyzed. The effective incorporation of CNC resulted in an increase in moduli and stress at yield besides in an increased thermomechanical stability, reaching the percolation threshold at a 3 wt% CNC as determined theoretically. Nevertheless, above the percolation threshold, the presence of agglomerates reduced slightly these values. The prepared nanocomposites showed increased hydrophilicity after CNC addition. |
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