Sintering behaviour of nanostructured glass-ceramic glazes

The thermal behaviour of a glass-ceramic glaze based on the system SiO2-CaO-ZnO-Al2O3 has been evaluated. Frit and kaolin were ball milling using dispersants and binders, and deposited on a green clay based ceramic support. The evolution of the glaze during the sintering step was observed that consi...

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Detalles Bibliográficos
Autores: Jiménez Reinosa, Julián, Rubio Marcos, Fernando, Solera Carlavilla, M. Elena, Bengochea, M. A., Fernández Lozano, José Francisco
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2010
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/376639
Acceso en línea:http://hdl.handle.net/10261/376639
https://www.scopus.com/inward/record.uri?eid=2-s2.0-77954085549&doi=10.1016%2fj.ceramint.2010.03.029&partnerID=40&md5=ad587ab06630f1990ec3a5b8c93bb00e
Access Level:acceso abierto
Palabra clave:Sintering
Microstructure-final
Glass ceramics
Structural applications
Pyroxenes
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spelling Sintering behaviour of nanostructured glass-ceramic glazesJiménez Reinosa, JuliánRubio Marcos, FernandoSolera Carlavilla, M. ElenaBengochea, M. A.Fernández Lozano, José FranciscoSinteringMicrostructure-finalGlass ceramicsStructural applicationsPyroxenesThe thermal behaviour of a glass-ceramic glaze based on the system SiO2-CaO-ZnO-Al2O3 has been evaluated. Frit and kaolin were ball milling using dispersants and binders, and deposited on a green clay based ceramic support. The evolution of the glaze during the sintering step was observed that consisted of a glassy matrix, particles from kaolin and particles from frit. Particles from frit formed a nanostructure of interconnected nanoparticles. Pyroxenes devitrified from the glassy matrix and at higher temperatures they were dissolved in the glassy matrix. Both successes contributed to the final observed nanostructure produced by a spinodal decomposition process in which the crystalline phase had a pyroxene composition. © 2010 Elsevier Ltd and Techna Group S.r.l.The authors thank to the projects MAT2007-66845-C02-01 and CENIT DOMINO by the financial support. Dr. F. Rubio- Marcos thanks the FPI-CAM-FSE program for the research grant.Peer reviewedElsevierAgencia Estatal de Investigación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252010info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/376639https://www.scopus.com/inward/record.uri?eid=2-s2.0-77954085549&doi=10.1016%2fj.ceramint.2010.03.029&partnerID=40&md5=ad587ab06630f1990ec3a5b8c93bb00ereponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MEC//MAT2007-66845-C02-01Ceramics Internationalhttps://doi.org/10.1016/j.ceramint.2010.03.029Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3766392026-05-22T06:33:51Z
dc.title.none.fl_str_mv Sintering behaviour of nanostructured glass-ceramic glazes
title Sintering behaviour of nanostructured glass-ceramic glazes
spellingShingle Sintering behaviour of nanostructured glass-ceramic glazes
Jiménez Reinosa, Julián
Sintering
Microstructure-final
Glass ceramics
Structural applications
Pyroxenes
title_short Sintering behaviour of nanostructured glass-ceramic glazes
title_full Sintering behaviour of nanostructured glass-ceramic glazes
title_fullStr Sintering behaviour of nanostructured glass-ceramic glazes
title_full_unstemmed Sintering behaviour of nanostructured glass-ceramic glazes
title_sort Sintering behaviour of nanostructured glass-ceramic glazes
dc.creator.none.fl_str_mv Jiménez Reinosa, Julián
Rubio Marcos, Fernando
Solera Carlavilla, M. Elena
Bengochea, M. A.
Fernández Lozano, José Francisco
author Jiménez Reinosa, Julián
author_facet Jiménez Reinosa, Julián
Rubio Marcos, Fernando
Solera Carlavilla, M. Elena
Bengochea, M. A.
Fernández Lozano, José Francisco
author_role author
author2 Rubio Marcos, Fernando
Solera Carlavilla, M. Elena
Bengochea, M. A.
Fernández Lozano, José Francisco
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Agencia Estatal de Investigación (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Sintering
Microstructure-final
Glass ceramics
Structural applications
Pyroxenes
topic Sintering
Microstructure-final
Glass ceramics
Structural applications
Pyroxenes
description The thermal behaviour of a glass-ceramic glaze based on the system SiO2-CaO-ZnO-Al2O3 has been evaluated. Frit and kaolin were ball milling using dispersants and binders, and deposited on a green clay based ceramic support. The evolution of the glaze during the sintering step was observed that consisted of a glassy matrix, particles from kaolin and particles from frit. Particles from frit formed a nanostructure of interconnected nanoparticles. Pyroxenes devitrified from the glassy matrix and at higher temperatures they were dissolved in the glassy matrix. Both successes contributed to the final observed nanostructure produced by a spinodal decomposition process in which the crystalline phase had a pyroxene composition. © 2010 Elsevier Ltd and Techna Group S.r.l.
publishDate 2010
dc.date.none.fl_str_mv 2010
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/376639
https://www.scopus.com/inward/record.uri?eid=2-s2.0-77954085549&doi=10.1016%2fj.ceramint.2010.03.029&partnerID=40&md5=ad587ab06630f1990ec3a5b8c93bb00e
url http://hdl.handle.net/10261/376639
https://www.scopus.com/inward/record.uri?eid=2-s2.0-77954085549&doi=10.1016%2fj.ceramint.2010.03.029&partnerID=40&md5=ad587ab06630f1990ec3a5b8c93bb00e
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MEC//MAT2007-66845-C02-01
Ceramics International
https://doi.org/10.1016/j.ceramint.2010.03.029
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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