Effect of different compatibilizers on injection-molded green composite pieces based on polylactide filled with almond shell flour
[EN] Green composites made of polylactide (PLA) filled with almond shell flour (ASF) at a constant weight content of 25¿wt.-% were manufactured by injection molding. In order to increase the interfacial adhesion between the biopolymer and the lignocellulosic fillers, three different compatibilizers...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2018 |
| País: | España |
| Institución: | Universitat Politècnica de València (UPV) |
| Repositorio: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| Idioma: | inglés |
| OAI Identifier: | oai:riunet.upv.es:10251/141457 |
| Acceso en línea: | https://riunet.upv.es/handle/10251/141457 |
| Access Level: | acceso abierto |
| Palabra clave: | PLA Multi-functional epoxy-based styrene-acrylic oligomer Aromatic carbodiimide Maleinized linseed oil Agro-food waste CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA |
| Sumario: | [EN] Green composites made of polylactide (PLA) filled with almond shell flour (ASF) at a constant weight content of 25¿wt.-% were manufactured by injection molding. In order to increase the interfacial adhesion between the biopolymer and the lignocellulosic fillers, three different compatibilizers were tested, namely multi-functional epoxy-based styrene-acrylic oligomer (ESAO), aromatic carbodiimide (AC), and maleinized linseed oil (MLO). The effect of each compatibilizer on the thermal, mechanical, and thermomechanical properties and water uptake of the injection-molded PLA/ASF pieces was analyzed. The obtained results indicated that all the here-studied compatibilizers had a positive influence on both the thermal stability and the mechanical and thermomechanical performance of the green composite pieces but low impact on their water uptake profile. In addition, the morphological analysis performed at the fracture surfaces of the green composite pieces revealed that the filler¿matrix gap was substantially reduced. Among the tested compatibilizers, ESAO and MLO yielded the highest performance in terms of mechanical strength and ductility, respectively. In the case of MLO, it also offers the advantage of being a plant-derived additive so that its application in green composites positively contributes to the development of sustainable polymer technologies. |
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