Quantitative colorimetric-imaging analysis of nickel in iron meteorites
A quantitative analytical imaging approach for determining the nickel content of metallic meteorites is proposed. The approach uses a digital image of a series of standard solutions of the nickel-dimethylglyoxime coloured chelate and a meteorite sample solution subjected to the same treatment as the...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2011 |
| País: | España |
| Institución: | Universitat Politècnica de València (UPV) |
| Repositorio: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| Idioma: | inglés |
| OAI Identifier: | oai:riunet.upv.es:10251/47485 |
| Acceso en línea: | https://riunet.upv.es/handle/10251/47485 |
| Access Level: | acceso abierto |
| Palabra clave: | CCD Colorimetric-imaging analysis ImageJ Meteorite Nickel Visible spectrophotometry Analyte concentration Analytical equipment Analytical signals Calibration graphs Digital image Dimethylglyoxime Imaging analysis Iron meteorites Measuring instruments National Institutes of Health Numerical values Public domain softwares Sample solution Spectro-photometric method Standard solutions Cameras Color Colorimetric analysis Colorimetry Cost benefit analysis Cost effectiveness Instruments Iron Meteorites Spectrophotometers Spectrophotometry Standards Article Astronomy Chemistry Economics Meteoroids INGENIERIA DE LA CONSTRUCCION |
| Sumario: | A quantitative analytical imaging approach for determining the nickel content of metallic meteorites is proposed. The approach uses a digital image of a series of standard solutions of the nickel-dimethylglyoxime coloured chelate and a meteorite sample solution subjected to the same treatment as the nickel standards for quantitation. The image is processed with suitable software to assign a colour-dependent numerical value (analytical signal) to each standard. Such a value is directly proportional to the analyte concentration, which facilitates construction of a calibration graph where the value for the unknown sample can be interpolated to calculate the nickel content of the meteorite. The results thus obtained were validated by comparison with the official, ISO-endorsed spectrophotometric method for nickel. The proposed method is fairly simple and inexpensive; in fact, it uses a commercially available digital camera as measuring instrument and the images it provides are processed with highly user-friendly public domain software (specifically, ImageJ, developed by the National Institutes of Health and freely available for download on the Internet). In a scenario dominated by increasingly sophisticated and expensive equipment, the proposed method provides a cost-effective alternative based on simple, robust hardware that is affordable and can be readily accessed worldwide. This can be especially advantageous for countries were available resources for analytical equipment investments are scant. The proposed method is essentially an adaptation of classical chemical analysis to current, straightforward, robust, cost-effective instrumentation. © 2010 Elsevier B.V. All rights reserved. |
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