Copper based hydrophobic ceramic nanocoating
A mechanism for the development of nanocoatings for the tiles industry by using copper nanoparticles has been proposed. A standard processing procedure in which ceramics were fast-firing at 1200°C in air atmosphere simulating an industrial process was followed. The ceramic nanocoating was multifunct...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2012 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/376654 |
| Acceso en línea: | http://hdl.handle.net/10261/376654 |
| Access Level: | acceso abierto |
| Palabra clave: | Microstructure-final Nanostructure-final Functional applications Hydrophobicity glaze |
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Copper based hydrophobic ceramic nanocoatingJiménez Reinosa, JuliánRomero Fanego, Juan JoséJaquotot, P.Bengochea, M.A.Fernández Lozano, José FranciscoMicrostructure-finalNanostructure-finalFunctional applicationsHydrophobicity glazeA mechanism for the development of nanocoatings for the tiles industry by using copper nanoparticles has been proposed. A standard processing procedure in which ceramics were fast-firing at 1200°C in air atmosphere simulating an industrial process was followed. The ceramic nanocoating was multifunctional having shine metallic aspect and hydrophobic characteristics. The surface crystallizations were studied by X-ray diffraction and corresponded to copper oxide nanocrystals. The hydrophobic response was based in the nanoroughness of the surface and correlated with the Cu+/Cu2+ ratio as determined by XANES. The cellular nano microstructure look biomimetic with the one of hydrophobic leafs. The development of the cellular nano microstructure was based on the Rayleigh-Bernard cells of a saturated glass during cooling in which thermal convection currents allow the crystallization of nanoparticles at the surface of the glass. © 2011 Elsevier Ltd.The authors are grateful to I. Lorite and P. Leret for their collaboration and discussion, and to M. Parrondo for his help in the figure of models. They are also grateful to F. Jimenez-Villacorta and J. A. Gallastegui for their very valuable help about the measurements in ESRF. Finally the authors would like to thank to the projects MAT2010-21088-C03-01 and CENIT DOMINO for the financial support.Appendix A. Supplementary data (Video)Peer reviewedElsevier BVAgencia Estatal de Investigación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2025202520122025info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/376654reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésInglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MICINN//MAT2010-21088-C03-01https://doi.org/10.1016/j.jeurceramsoc.2011.08.013Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3766542026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Copper based hydrophobic ceramic nanocoating |
| title |
Copper based hydrophobic ceramic nanocoating |
| spellingShingle |
Copper based hydrophobic ceramic nanocoating Jiménez Reinosa, Julián Microstructure-final Nanostructure-final Functional applications Hydrophobicity glaze |
| title_short |
Copper based hydrophobic ceramic nanocoating |
| title_full |
Copper based hydrophobic ceramic nanocoating |
| title_fullStr |
Copper based hydrophobic ceramic nanocoating |
| title_full_unstemmed |
Copper based hydrophobic ceramic nanocoating |
| title_sort |
Copper based hydrophobic ceramic nanocoating |
| dc.creator.none.fl_str_mv |
Jiménez Reinosa, Julián Romero Fanego, Juan José Jaquotot, P. Bengochea, M.A. Fernández Lozano, José Francisco |
| author |
Jiménez Reinosa, Julián |
| author_facet |
Jiménez Reinosa, Julián Romero Fanego, Juan José Jaquotot, P. Bengochea, M.A. Fernández Lozano, José Francisco |
| author_role |
author |
| author2 |
Romero Fanego, Juan José Jaquotot, P. Bengochea, M.A. Fernández Lozano, José Francisco |
| author2_role |
author author author author |
| dc.contributor.none.fl_str_mv |
Agencia Estatal de Investigación (España) Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Microstructure-final Nanostructure-final Functional applications Hydrophobicity glaze |
| topic |
Microstructure-final Nanostructure-final Functional applications Hydrophobicity glaze |
| description |
A mechanism for the development of nanocoatings for the tiles industry by using copper nanoparticles has been proposed. A standard processing procedure in which ceramics were fast-firing at 1200°C in air atmosphere simulating an industrial process was followed. The ceramic nanocoating was multifunctional having shine metallic aspect and hydrophobic characteristics. The surface crystallizations were studied by X-ray diffraction and corresponded to copper oxide nanocrystals. The hydrophobic response was based in the nanoroughness of the surface and correlated with the Cu+/Cu2+ ratio as determined by XANES. The cellular nano microstructure look biomimetic with the one of hydrophobic leafs. The development of the cellular nano microstructure was based on the Rayleigh-Bernard cells of a saturated glass during cooling in which thermal convection currents allow the crystallization of nanoparticles at the surface of the glass. © 2011 Elsevier Ltd. |
| publishDate |
2012 |
| dc.date.none.fl_str_mv |
2012 2025 2025 2025 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Postprint info:eu-repo/semantics/acceptedVersion |
| format |
article |
| status_str |
acceptedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/376654 |
| url |
http://hdl.handle.net/10261/376654 |
| dc.language.none.fl_str_mv |
Inglés Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
#PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MICINN//MAT2010-21088-C03-01 https://doi.org/10.1016/j.jeurceramsoc.2011.08.013 Sí |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Elsevier BV |
| publisher.none.fl_str_mv |
Elsevier BV |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869406997868183552 |
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15.811543 |