Combining vegetable oils and bioactive compounds via inverse vulcanization for antioxidant and antimicrobial materials

The current great concern about plastic pollution opens up opportunities for the production of more sustainable polymers. Inverse vulcanization has emerged as a novel procedure to obtain inorganic-organic hybrid polymeric materials. Sulfur is attained as a by-product of oil refining production and m...

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Detalles Bibliográficos
Autores: Cubero Cardoso, Juan, Gómez-Villegas, Patricia, Santos Martín, María, Sayago Gómez, Ana, Fernández Recamales, María Ángeles, Fernández de Villarán San Juan, Rubén, Cuadri Vega, Antonio Abad, Martín Alfonso, José Enrique, Borja Padilla, Rafael, González Fermoso, Fernando, León Bañares, Rosa María, Urbano Baena, Juan
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/23018
Acceso en línea:https://hdl.handle.net/10272/23018
Access Level:acceso abierto
Palabra clave:Inverse vulcanization
Bioactive compounds
Valorization
Polysulfide
Copolymers
23 Química
2301 Química Analítica
2302 Bioquímica
2303 Química Inorgánica
Descripción
Sumario:The current great concern about plastic pollution opens up opportunities for the production of more sustainable polymers. Inverse vulcanization has emerged as a novel procedure to obtain inorganic-organic hybrid polymeric materials. Sulfur is attained as a by-product of oil refining production and makes inverse vulcanization a sustainable process due to a large amount of sulfur without a useful life. In previous studies, vegetable oils were used as a comonomer with sulfur to form copolymers based on sustainable raw material. Nevertheless, compounds from agro-wastes, could be a third comonomer that improves new copolymers bio-applications. In this study, a new series of copolymers with castor oil as vegetable oil and sulfur was formulated by adding a third compound bearing double bonds or heteroatoms. A study was conducted to assess the antimicrobial capacity and antioxidant activity of the copolymers obtained to demonstrate the benefits of adding a new comonomer to improve their bioactivity.