The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
A superplasticizing admixture of natural origin, lignosulfonate (LS), was incorporated to air lime mortars sometimes modified with a pozzolanic additive, metakaolin, to obtain a new range of repair mortars to be applied in Built Heritage. LS improved the flowability of the air lime samples and showe...
| Autores: | , , , , , |
|---|---|
| Formato: | capítulo de livro |
| Fecha de publicación: | 2016 |
| País: | España |
| Recursos: | Universidad de Navarra |
| Repositorio: | Dadun. Depósito Académico Digital de la Universidad de Navarra |
| Idioma: | inglés |
| OAI Identifier: | oai:dadun.unav.edu:10171/43006 |
| Acesso em linha: | https://hdl.handle.net/10171/43006 |
| Access Level: | acceso abierto |
| Palavra-chave: | Materias Investigacion::Química Mortars Superplasticizers |
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The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortarsPerez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7dfDuran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1dSirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610dNavarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204Materias Investigacion::QuímicaMortarsSuperplasticizersA superplasticizing admixture of natural origin, lignosulfonate (LS), was incorporated to air lime mortars sometimes modified with a pozzolanic additive, metakaolin, to obtain a new range of repair mortars to be applied in Built Heritage. LS improved the flowability of the air lime samples and showed good slump retention over time: for example, after 150 minutes of the air lime pastes preparation, blends with LS lost only ca. 13% of the slump value. Experimental results showed that LS interfered with the carbonation due to its ability to form Ca2+ complexes. Adsorption isotherms and zeta potential measurements showed that LS was scarcely adsorbed onto lime and C-S-H particles. Due to its branchy structure, LS exhibited an adsorption mechanism leading to steric hindrance as the main responsible mechanism for avoiding flocculation. The presence of free LS molecules in the dispersion was seen to improve the plasticizing effect of this polymer. Flexural and compressive strengths as well as the durability in the face of freezing-thawing cycles of these mortars were also determined to assess the applicability of these repair mortars.Aristotle University of ThessalonikiDadun. Depósito Académico Digital Universidad de Navarra20172017-02-1720162016-01-0120162016-01-01book parthttp://purl.org/coar/resource_type/c_3248info:eu-repo/semantics/bookPartapplication/pdfhttps://hdl.handle.net/10171/43006reponame:Dadun. Depósito Académico Digital de la Universidad de Navarrainstname:Universidad de NavarraInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:dadun.unav.edu:10171/430062026-06-21T12:47:57Z |
| dc.title.none.fl_str_mv |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars |
| title |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars |
| spellingShingle |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df Materias Investigacion::Química Mortars Superplasticizers |
| title_short |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars |
| title_full |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars |
| title_fullStr |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars |
| title_full_unstemmed |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars |
| title_sort |
The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars |
| dc.creator.none.fl_str_mv |
Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df Duran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1d Sirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610d Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54 Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8 Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204 |
| author |
Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df |
| author_facet |
Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df Duran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1d Sirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610d Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54 Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8 Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204 |
| author_role |
author |
| author2 |
Duran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1d Sirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610d Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54 Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8 Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204 |
| author2_role |
author author author author author |
| dc.contributor.none.fl_str_mv |
Dadun. Depósito Académico Digital Universidad de Navarra |
| dc.subject.none.fl_str_mv |
Materias Investigacion::Química Mortars Superplasticizers |
| topic |
Materias Investigacion::Química Mortars Superplasticizers |
| description |
A superplasticizing admixture of natural origin, lignosulfonate (LS), was incorporated to air lime mortars sometimes modified with a pozzolanic additive, metakaolin, to obtain a new range of repair mortars to be applied in Built Heritage. LS improved the flowability of the air lime samples and showed good slump retention over time: for example, after 150 minutes of the air lime pastes preparation, blends with LS lost only ca. 13% of the slump value. Experimental results showed that LS interfered with the carbonation due to its ability to form Ca2+ complexes. Adsorption isotherms and zeta potential measurements showed that LS was scarcely adsorbed onto lime and C-S-H particles. Due to its branchy structure, LS exhibited an adsorption mechanism leading to steric hindrance as the main responsible mechanism for avoiding flocculation. The presence of free LS molecules in the dispersion was seen to improve the plasticizing effect of this polymer. Flexural and compressive strengths as well as the durability in the face of freezing-thawing cycles of these mortars were also determined to assess the applicability of these repair mortars. |
| publishDate |
2016 |
| dc.date.none.fl_str_mv |
2016 2016-01-01 2016 2016-01-01 2017 2017-02-17 |
| dc.type.none.fl_str_mv |
book part http://purl.org/coar/resource_type/c_3248 |
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info:eu-repo/semantics/bookPart |
| format |
bookPart |
| dc.identifier.none.fl_str_mv |
https://hdl.handle.net/10171/43006 |
| url |
https://hdl.handle.net/10171/43006 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 |
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info:eu-repo/semantics/openAccess |
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open access http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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application/pdf |
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Aristotle University of Thessaloniki |
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Aristotle University of Thessaloniki |
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reponame:Dadun. Depósito Académico Digital de la Universidad de Navarra instname:Universidad de Navarra |
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Universidad de Navarra |
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Dadun. Depósito Académico Digital de la Universidad de Navarra |
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Dadun. Depósito Académico Digital de la Universidad de Navarra |
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15,300724 |