The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars

A superplasticizing admixture of natural origin, lignosulfonate (LS), was incorporated to air lime mortars sometimes modified with a pozzolanic additive, metakaolin, to obtain a new range of repair mortars to be applied in Built Heritage. LS improved the flowability of the air lime samples and showe...

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Autores: Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df, Duran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1d, Sirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610d, Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54, Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8, Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
Formato: capítulo de livro
Fecha de publicación:2016
País:España
Recursos:Universidad de Navarra
Repositorio:Dadun. Depósito Académico Digital de la Universidad de Navarra
Idioma:inglés
OAI Identifier:oai:dadun.unav.edu:10171/43006
Acesso em linha:https://hdl.handle.net/10171/43006
Access Level:acceso abierto
Palavra-chave:Materias Investigacion::Química
Mortars
Superplasticizers
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spelling The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortarsPerez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7dfDuran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1dSirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610dNavarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204Materias Investigacion::QuímicaMortarsSuperplasticizersA superplasticizing admixture of natural origin, lignosulfonate (LS), was incorporated to air lime mortars sometimes modified with a pozzolanic additive, metakaolin, to obtain a new range of repair mortars to be applied in Built Heritage. LS improved the flowability of the air lime samples and showed good slump retention over time: for example, after 150 minutes of the air lime pastes preparation, blends with LS lost only ca. 13% of the slump value. Experimental results showed that LS interfered with the carbonation due to its ability to form Ca2+ complexes. Adsorption isotherms and zeta potential measurements showed that LS was scarcely adsorbed onto lime and C-S-H particles. Due to its branchy structure, LS exhibited an adsorption mechanism leading to steric hindrance as the main responsible mechanism for avoiding flocculation. The presence of free LS molecules in the dispersion was seen to improve the plasticizing effect of this polymer. Flexural and compressive strengths as well as the durability in the face of freezing-thawing cycles of these mortars were also determined to assess the applicability of these repair mortars.Aristotle University of ThessalonikiDadun. Depósito Académico Digital Universidad de Navarra20172017-02-1720162016-01-0120162016-01-01book parthttp://purl.org/coar/resource_type/c_3248info:eu-repo/semantics/bookPartapplication/pdfhttps://hdl.handle.net/10171/43006reponame:Dadun. Depósito Académico Digital de la Universidad de Navarrainstname:Universidad de NavarraInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:dadun.unav.edu:10171/430062026-06-21T12:47:57Z
dc.title.none.fl_str_mv The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
title The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
spellingShingle The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df
Materias Investigacion::Química
Mortars
Superplasticizers
title_short The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
title_full The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
title_fullStr The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
title_full_unstemmed The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
title_sort The use of a lignosulfonate superplasticizer in repair air lime-metakaolin mortars
dc.creator.none.fl_str_mv Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df
Duran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1d
Sirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610d
Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54
Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8
Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
author Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df
author_facet Perez-Nicolas, M. (María)|||/items/8615ce55-1234-42ac-991a-a320ec2ab7df
Duran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1d
Sirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610d
Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54
Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8
Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
author_role author
author2 Duran-Benito, A. (Adrian)|||/items/7059fa82-fd72-4355-8d76-0fd12a2e4d1d
Sirera-Bejarano, R. (Rafael)|||/items/dd5ea901-439c-4cbe-9798-b1ad5efb610d
Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54
Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8
Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Dadun. Depósito Académico Digital Universidad de Navarra
dc.subject.none.fl_str_mv Materias Investigacion::Química
Mortars
Superplasticizers
topic Materias Investigacion::Química
Mortars
Superplasticizers
description A superplasticizing admixture of natural origin, lignosulfonate (LS), was incorporated to air lime mortars sometimes modified with a pozzolanic additive, metakaolin, to obtain a new range of repair mortars to be applied in Built Heritage. LS improved the flowability of the air lime samples and showed good slump retention over time: for example, after 150 minutes of the air lime pastes preparation, blends with LS lost only ca. 13% of the slump value. Experimental results showed that LS interfered with the carbonation due to its ability to form Ca2+ complexes. Adsorption isotherms and zeta potential measurements showed that LS was scarcely adsorbed onto lime and C-S-H particles. Due to its branchy structure, LS exhibited an adsorption mechanism leading to steric hindrance as the main responsible mechanism for avoiding flocculation. The presence of free LS molecules in the dispersion was seen to improve the plasticizing effect of this polymer. Flexural and compressive strengths as well as the durability in the face of freezing-thawing cycles of these mortars were also determined to assess the applicability of these repair mortars.
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-01-01
2016
2016-01-01
2017
2017-02-17
dc.type.none.fl_str_mv book part
http://purl.org/coar/resource_type/c_3248
dc.type.openaire.fl_str_mv info:eu-repo/semantics/bookPart
format bookPart
dc.identifier.none.fl_str_mv https://hdl.handle.net/10171/43006
url https://hdl.handle.net/10171/43006
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Aristotle University of Thessaloniki
publisher.none.fl_str_mv Aristotle University of Thessaloniki
dc.source.none.fl_str_mv reponame:Dadun. Depósito Académico Digital de la Universidad de Navarra
instname:Universidad de Navarra
instname_str Universidad de Navarra
reponame_str Dadun. Depósito Académico Digital de la Universidad de Navarra
collection Dadun. Depósito Académico Digital de la Universidad de Navarra
repository.name.fl_str_mv
repository.mail.fl_str_mv
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