Structural caracterization of silver(I) complexes of diphenylmethanimine and (diphenylmethyleneamino)diphenylphosphine

The reaction of NH=CPH2 with the silver species [AgX(PPh3)] (X=ClO4, SO3CF3) affords the derivatives [Ag(PPh3)(NH=CPh2)]X. Complexes [Ag(Ph2PN=CPh2)2]X (X=Cl, ClO4, SO3CF3) have been obtained from Ph2PN=CPh2 and the corresponding silver salt AgX. X-ray diffraction studies have been carried out for f...

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Detalles Bibliográficos
Autores: Codina, A., Crespo, O., Fernández, E.J. [0000-0002-6501-744X], Jones, P.G., Laguna, A. [0000-0003-1984-7538], López-De-Luzuriaga, J.M. [0000-0001-5767-8734], Olmos, M.E. [0000-0001-8890-8977]
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2003
País:España
Institución:Universidad de La Rioja (UR)
Repositorio:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc6841b750603269e80584
Acceso en línea:https://investigacion.unirioja.es/documentos/5bbc6841b750603269e80584
Access Level:acceso abierto
Palabra clave:Crystal structures
Ketimine complexes
Silver complexes
Descripción
Sumario:The reaction of NH=CPH2 with the silver species [AgX(PPh3)] (X=ClO4, SO3CF3) affords the derivatives [Ag(PPh3)(NH=CPh2)]X. Complexes [Ag(Ph2PN=CPh2)2]X (X=Cl, ClO4, SO3CF3) have been obtained from Ph2PN=CPh2 and the corresponding silver salt AgX. X-ray diffraction studies have been carried out for four of the derivatives. © 2002 Elsevier Science B.V. All rights reserved.

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