Determination of vibrational polarizabilities and hyperpolarizabilities using field-induced coordinates

An analytical set of field-induced coordinates is defined and is used to show that the vibrational degrees of freedom required to completely describe nuclear relaxation polarizabilities and hyperpolarizabilities is reduced from 3N-6 to a relatively small number. As this number does not depend upon t...

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Detalles Bibliográficos
Autores: Luis Luis, Josep Maria, Duran i Portas, Miquel, Champagne, Benoît, Kirtman, Bernard
Tipo de recurso: artículo
Fecha de publicación:2000
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/3226
Acceso en línea:http://hdl.handle.net/10256/3226
Access Level:acceso abierto
Palabra clave:Aproximació, Teoria de l'
Dinàmica molecular
Enllaços químics
Estructura molecular
Molècules
Transformacions (Matemàtica)
Polarització (Electricitat)
Approximation theory
Chemical bonds
Molecular structure
Molecular dynamics
Molecules
Polarization (Electricity)
Transformations (Mathematics)
Descripción
Sumario:An analytical set of field-induced coordinates is defined and is used to show that the vibrational degrees of freedom required to completely describe nuclear relaxation polarizabilities and hyperpolarizabilities is reduced from 3N-6 to a relatively small number. As this number does not depend upon the size of the molecule, the process provides computational advantages. A method is provided to separate anharmonic contributions from harmonic contributions as well as effective mechanical from electrical anharmonicity. The procedures are illustrated by Hartree-Fock calculations, indicating that anharmonicity can be very important