An Efficient Method for the Copper(II)-promoted Stereoselective Iodofunctionalization of Alkenes
A mixture of iodine and CuO·HBF4 reacts stereoselectively with alkenes in the presence of a wide variety of nucleophiles (water, MeOH, HCO2H, AcOH, EtCO2H, NaNO2, KSCN, NaSO 2Ar, LiCl, LiBr, Nal, Et3SiH, and MeOPh) to give the corresponding 2-functionalized iodo compounds. A regio-chemistry study is...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1990 |
| País: | España |
| Institución: | Universidad de La Rioja (UR) |
| Repositorio: | RIUR. Repositorio Institucional de la Universidad de La Rioja |
| OAI Identifier: | oai:portal.dialnet.es:doc/5bbc68bcb750603269e80e9b |
| Acceso en línea: | https://investigacion.unirioja.es/documentos/5bbc68bcb750603269e80e9b |
| Access Level: | acceso abierto |
| Sumario: | A mixture of iodine and CuO·HBF4 reacts stereoselectively with alkenes in the presence of a wide variety of nucleophiles (water, MeOH, HCO2H, AcOH, EtCO2H, NaNO2, KSCN, NaSO 2Ar, LiCl, LiBr, Nal, Et3SiH, and MeOPh) to give the corresponding 2-functionalized iodo compounds. A regio-chemistry study is also reported. |
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