Inverse core-rim microstructure in (Ti,Ta)(C,N)-based cermets developed by a mechanically induced self-sustaining reaction
Cermets with a nominal composition (Ti 0.8Ta 0.2C 0.5N 0.5- 20 wt.% Co) were synthesised by a mechanically induced self-sustaining reaction (MSR) process from stoichiometric elemental powder blends. The MSR allowed the production of a complex (Ti,Ta)(C,N) solid solution, which was the raw material u...
| Autores: | , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2012 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/104049 |
| Acesso em linha: | http://hdl.handle.net/10261/104049 |
| Access Level: | acceso abierto |
| Palavra-chave: | Cermet Inverse core-rim Carbonitride Combustion synthesis Mechanochemistry |
| Resumo: | Cermets with a nominal composition (Ti 0.8Ta 0.2C 0.5N 0.5- 20 wt.% Co) were synthesised by a mechanically induced self-sustaining reaction (MSR) process from stoichiometric elemental powder blends. The MSR allowed the production of a complex (Ti,Ta)(C,N) solid solution, which was the raw material used for the sintering process. The pressureless sintering process was performed at temperatures between 1400 °C and 1600 °C in an inert atmosphere. The microstructural characterisation showed a complex microstructure composed of a ceramic phase with an unusual inverse core-rim structure and a Ti-Ta-Co intermetallic phase that acted as the binder. © 2011 Elsevier Ltd. All rights reserved. |
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