Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers

Pseudo-binary mixtures of different glycolipids, four different rhamnolipids (RL) and an alkyl polyglucoside (APG), with poly(diallyl-dimethylammonium chloride) (PDADMAC) have been studied in relation to their adsorption onto negatively charged surfaces to shed light on the impact of the molecular s...

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Detalles Bibliográficos
Autores: Fernández Peña, Laura, Guzmán Solís, Eduardo, Leonforte, Fabien, Serrano-Pueyo, Ana, Regulski, Krzysztof, Tournier-Couturier, Lucie, Ortega Gómez, Francisco, González Rubio, Ramón, Luengo, Gustavo
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/98983
Acceso en línea:https://hdl.handle.net/20.500.14352/98983
Access Level:acceso abierto
Palabra clave:544
Adsorption
Chlorine compounds
Hair care
Polyelectrolytes
Cosmetic
Química física (Química)
2307 Química Física
id ES_405ea5febb27ee79870d75ca2bb48e55
oai_identifier_str oai:docta.ucm.es:20.500.14352/98983
network_acronym_str ES
network_name_str España
repository_id_str
spelling Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymersFernández Peña, LauraGuzmán Solís, EduardoLeonforte, FabienSerrano-Pueyo, AnaRegulski, KrzysztofTournier-Couturier, LucieOrtega Gómez, FranciscoGonzález Rubio, RamónLuengo, Gustavo544AdsorptionChlorine compoundsHair carePolyelectrolytesCosmeticQuímica física (Química)2307 Química FísicaPseudo-binary mixtures of different glycolipids, four different rhamnolipids (RL) and an alkyl polyglucoside (APG), with poly(diallyl-dimethylammonium chloride) (PDADMAC) have been studied in relation to their adsorption onto negatively charged surfaces to shed light on the impact of the molecular structure of surfactants from natural sources (instead of synthetic surfactant, such as sodium laureth sulfate) on the adsorption of hair-conditioning polymers. For this purpose, the self-assembly of such mixtures in aqueous solution and their adsorption onto negatively charged surfaces mimicking the negative charge of damaged hair fibres have been studied combining experiments and self-consistent field (SCF) calculations. The results show that the specific physico-chemical properties of the surfactants (charge, number of sugar rings present in surfactant structure and length of the hydrocarbon length) play a main role in the control of the adsorption process, with the adsorption efficiency and hydration being improved in relation to conventional sulfate-based systems for mixtures of PDADMAC and glycolipids with the shortest alkyl chains. SCF calculations and Energy Dispersive X-Ray Spectroscopy (EDS) analysis on real hair confirmed such observations. The results allow one to assume that the characteristic of the surfactants, especially rhamnolipids, conditions positively the adsorption potential of polyelectrolytes in these model systems. This study provides important insights on the mechanisms underlying the performance of more complex but eco-friendly washing formulationsElsevierUniversidad Complutense de Madrid20202020-01-0120202020-01-01journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/98983reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/989832026-06-02T12:44:21Z
dc.title.none.fl_str_mv Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
title Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
spellingShingle Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
Fernández Peña, Laura
544
Adsorption
Chlorine compounds
Hair care
Polyelectrolytes
Cosmetic
Química física (Química)
2307 Química Física
title_short Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
title_full Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
title_fullStr Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
title_full_unstemmed Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
title_sort Effect of molecular structure of eco-friendly glycolipid biosurfactants on the adsorption of hair-care conditioning polymers
dc.creator.none.fl_str_mv Fernández Peña, Laura
Guzmán Solís, Eduardo
Leonforte, Fabien
Serrano-Pueyo, Ana
Regulski, Krzysztof
Tournier-Couturier, Lucie
Ortega Gómez, Francisco
González Rubio, Ramón
Luengo, Gustavo
author Fernández Peña, Laura
author_facet Fernández Peña, Laura
Guzmán Solís, Eduardo
Leonforte, Fabien
Serrano-Pueyo, Ana
Regulski, Krzysztof
Tournier-Couturier, Lucie
Ortega Gómez, Francisco
González Rubio, Ramón
Luengo, Gustavo
author_role author
author2 Guzmán Solís, Eduardo
Leonforte, Fabien
Serrano-Pueyo, Ana
Regulski, Krzysztof
Tournier-Couturier, Lucie
Ortega Gómez, Francisco
González Rubio, Ramón
Luengo, Gustavo
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 544
Adsorption
Chlorine compounds
Hair care
Polyelectrolytes
Cosmetic
Química física (Química)
2307 Química Física
topic 544
Adsorption
Chlorine compounds
Hair care
Polyelectrolytes
Cosmetic
Química física (Química)
2307 Química Física
description Pseudo-binary mixtures of different glycolipids, four different rhamnolipids (RL) and an alkyl polyglucoside (APG), with poly(diallyl-dimethylammonium chloride) (PDADMAC) have been studied in relation to their adsorption onto negatively charged surfaces to shed light on the impact of the molecular structure of surfactants from natural sources (instead of synthetic surfactant, such as sodium laureth sulfate) on the adsorption of hair-conditioning polymers. For this purpose, the self-assembly of such mixtures in aqueous solution and their adsorption onto negatively charged surfaces mimicking the negative charge of damaged hair fibres have been studied combining experiments and self-consistent field (SCF) calculations. The results show that the specific physico-chemical properties of the surfactants (charge, number of sugar rings present in surfactant structure and length of the hydrocarbon length) play a main role in the control of the adsorption process, with the adsorption efficiency and hydration being improved in relation to conventional sulfate-based systems for mixtures of PDADMAC and glycolipids with the shortest alkyl chains. SCF calculations and Energy Dispersive X-Ray Spectroscopy (EDS) analysis on real hair confirmed such observations. The results allow one to assume that the characteristic of the surfactants, especially rhamnolipids, conditions positively the adsorption potential of polyelectrolytes in these model systems. This study provides important insights on the mechanisms underlying the performance of more complex but eco-friendly washing formulations
publishDate 2020
dc.date.none.fl_str_mv 2020
2020-01-01
2020
2020-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/98983
url https://hdl.handle.net/20.500.14352/98983
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869406744765005824
score 15,81155

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