Methane hydrate formation in confined nanospace can surpass nature

<p> Natural methane hydrates are believed to be the largest source of hydrocarbons on Earth. These structures are formed in specific locations such as deep-sea sediments and the permafrost based on demanding conditions of high pressure and low temperature. Here we report that, by taking advant...

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Detalles Bibliográficos
Autores: Casco, Mirian E., Silvestre-Albero, Joaquín, Ramírez-Cuesta, Anibal J., Rey, Fernando, Jordá, Jose L., Bansode, Atul, Urakawa, Atsushi, Peral, Inma, Martínez-Escandell, Manuel, Kaneko, Katsumi, Rodríguez-Reinoso, Francisco
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305910
Acceso en línea:http://hdl.handle.net/2072/305910
https://doi.org/10.1038/ncomms7432
Access Level:acceso abierto
Descripción
Sumario:<p> Natural methane hydrates are believed to be the largest source of hydrocarbons on Earth. These structures are formed in specific locations such as deep-sea sediments and the permafrost based on demanding conditions of high pressure and low temperature. Here we report that, by taking advantage of the confinement effects on nanopore space, synthetic methane hydrates grow under mild conditions (3.5&thinsp;MPa and 2&thinsp;&deg;C), with faster kinetics (within minutes) than nature, fully reversibly and with a nominal stoichiometry that mimics nature. The formation of the hydrate structures in nanospace and their similarity to natural hydrates is confirmed using inelastic neutron scattering experiments and synchrotron X-ray powder diffraction. These findings may be a step towards the application of a smart synthesis of methane hydrates in energy-demanding applications (for example, transportation).</p>