Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization

[EN] Most valorization processes for biomass waste require dry raw material or at least a relatively low amount of residual humidity. In contrast, hydrothermal carbonization (HTC) is a valorization process for lignocellulosic biomass which uses water as a reaction medium. The product, hydrochar, can...

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Autores: Burguete Llorens, Pedro Luis, Hitzl, Martin, Modrego Latorre, Ruben, Ponce Ballester, Estefanía, Corma Canós, Avelino|||0000-0002-2232-3527, Renz, Michael|||0000-0002-1101-9562
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/83370
Acceso en línea:https://riunet.upv.es/handle/10251/83370
Access Level:acceso abierto
Palabra clave:Hydrothermal
Carbonization
Biomass
Lignocellulosic
QUIMICA INORGANICA
QUIMICA ORGANICA
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spelling Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonizationBurguete Llorens, Pedro LuisHitzl, MartinModrego Latorre, RubenPonce Ballester, EstefaníaCorma Canós, Avelino|||0000-0002-2232-3527Renz, Michael|||0000-0002-1101-9562HydrothermalCarbonizationBiomassLignocellulosicQUIMICA INORGANICAQUIMICA ORGANICA[EN] Most valorization processes for biomass waste require dry raw material or at least a relatively low amount of residual humidity. In contrast, hydrothermal carbonization (HTC) is a valorization process for lignocellulosic biomass which uses water as a reaction medium. The product, hydrochar, can be used as dry solid fuel making the post-process drying procedure much more energy-efficient. Herein, three lignocellulosic biomass waste feedstocks, i.e. the organic fraction of municipal solid waste (OFMSW), orange peel waste (OPW) and the residues of a pepper plantation, were processed by HTC on a ton scale and the product evaluated as solid fuel in form of pellets for domestic use (EN ISO 17225). A critical property of the product is the ash content which has to be adjusted by post-treatment. Ash content below the established limit was achieved by acid treatment with sulfuric acid. An implementation of the treatment into the pilot plant is straightforward. An organic liquid fraction was obtained as an additional effluent in the pilot plant depending on the biomass feedstock. For instance, limonene in a mixture with other monoterpenes was separated when orange peel waste was processed, constituting approximately 3 wt% of the dry matter. It is further shown at laboratory scale that the monoterpene mixture can be directly used or can easily be transformed into para-cymene, a fragrance compound, by catalytic dehydrogenation. Therefore, the HTC process can be considered as a source for valuable apolar platform molecules derived from lignocellulosic biomass waste in addition to the production of hydrochar.Authors are grateful for financial support from the EU (FP7-SME-2013-605178-NEWAPP) and from the Spanish Ministry of Economy and Competitiveness (Innpacto Programme, IPT-2012-0023-120000). We thank our NEWAPP partners (http://newapp-project.eu/en/partners.html), especially M. Ryberg and M. Owsianiak from the Technical University of Denmark (DTU) and L. Doyle from TTZ Bremerhaven, for fruitful discussions and valuable suggestions.Royal Society of ChemistryInstituto Universitario Mixto de Tecnología QuímicaEuropean CommissionMinisterio de Economía y CompetitividadRepositorio Institucional de la Universitat Politècnica de València Riunet20162016-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/83370reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengEuropean Commission https://doi.org/10.13039/501100000780 FP7 605178 New technological applications for wet biomass waste stream productsMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 IPT-2012-0023-120000 Métodos de extracción y evaluación de bioquímicos, obtenidos en el proceso industrial de carbonización hidrotermal de Ingelia a partir de diferentes tipos de biomasas, y mediante ensayos en la planta prototipo de Ingelia.open accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/833702026-06-13T07:49:27Z
dc.title.none.fl_str_mv Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
title Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
spellingShingle Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
Burguete Llorens, Pedro Luis
Hydrothermal
Carbonization
Biomass
Lignocellulosic
QUIMICA INORGANICA
QUIMICA ORGANICA
title_short Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
title_full Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
title_fullStr Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
title_full_unstemmed Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
title_sort Fuel and chemicals from wet lignocellulosic biomass waste streams by hydrothermal carbonization
dc.creator.none.fl_str_mv Burguete Llorens, Pedro Luis
Hitzl, Martin
Modrego Latorre, Ruben
Ponce Ballester, Estefanía
Corma Canós, Avelino|||0000-0002-2232-3527
Renz, Michael|||0000-0002-1101-9562
author Burguete Llorens, Pedro Luis
author_facet Burguete Llorens, Pedro Luis
Hitzl, Martin
Modrego Latorre, Ruben
Ponce Ballester, Estefanía
Corma Canós, Avelino|||0000-0002-2232-3527
Renz, Michael|||0000-0002-1101-9562
author_role author
author2 Hitzl, Martin
Modrego Latorre, Ruben
Ponce Ballester, Estefanía
Corma Canós, Avelino|||0000-0002-2232-3527
Renz, Michael|||0000-0002-1101-9562
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Instituto Universitario Mixto de Tecnología Química
European Commission
Ministerio de Economía y Competitividad
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Hydrothermal
Carbonization
Biomass
Lignocellulosic
QUIMICA INORGANICA
QUIMICA ORGANICA
topic Hydrothermal
Carbonization
Biomass
Lignocellulosic
QUIMICA INORGANICA
QUIMICA ORGANICA
description [EN] Most valorization processes for biomass waste require dry raw material or at least a relatively low amount of residual humidity. In contrast, hydrothermal carbonization (HTC) is a valorization process for lignocellulosic biomass which uses water as a reaction medium. The product, hydrochar, can be used as dry solid fuel making the post-process drying procedure much more energy-efficient. Herein, three lignocellulosic biomass waste feedstocks, i.e. the organic fraction of municipal solid waste (OFMSW), orange peel waste (OPW) and the residues of a pepper plantation, were processed by HTC on a ton scale and the product evaluated as solid fuel in form of pellets for domestic use (EN ISO 17225). A critical property of the product is the ash content which has to be adjusted by post-treatment. Ash content below the established limit was achieved by acid treatment with sulfuric acid. An implementation of the treatment into the pilot plant is straightforward. An organic liquid fraction was obtained as an additional effluent in the pilot plant depending on the biomass feedstock. For instance, limonene in a mixture with other monoterpenes was separated when orange peel waste was processed, constituting approximately 3 wt% of the dry matter. It is further shown at laboratory scale that the monoterpene mixture can be directly used or can easily be transformed into para-cymene, a fragrance compound, by catalytic dehydrogenation. Therefore, the HTC process can be considered as a source for valuable apolar platform molecules derived from lignocellulosic biomass waste in addition to the production of hydrochar.
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/83370
url https://riunet.upv.es/handle/10251/83370
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission https://doi.org/10.13039/501100000780 FP7 605178 New technological applications for wet biomass waste stream products
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 IPT-2012-0023-120000 Métodos de extracción y evaluación de bioquímicos, obtenidos en el proceso industrial de carbonización hidrotermal de Ingelia a partir de diferentes tipos de biomasas, y mediante ensayos en la planta prototipo de Ingelia.
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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