Application of a Fuzzy Logic Based Methodology to Validate the Hydrochemical Characterization and Determining Seasonal Influence of a Watershed Affected by Acid Mine Drainage

The Odiel River Basin, located in the Iberian Pyrite Belt (IPB), is heavily affected by acid mine drainage (AMD), which occurs when pyritic minerals from sulfide mining areas are exposed to atmospheric, hydrological or biological weathering. This paper presents a hydrochemical characterization of pa...

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Detalles Bibliográficos
Autores: Dávila Martín, José Miguel, Miguel Sarmiento, Aguasanta, Aroba Páez, Javier, Fortes Garrido, Juan Carlos, Grande Gil, José Antonio, Santisteban Fernández, María, Córdoba García, Francisco, Leiva, Mercedes, Luís, Ana Teresa
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/19866
Acceso en línea:http://hdl.handle.net/10272/19866
Access Level:acceso abierto
Palabra clave:Odiel River Basin
Seasonal influence
Iberian Pyrite Belt
Metal concentrations
Acidity
Polluted water
Descripción
Sumario:The Odiel River Basin, located in the Iberian Pyrite Belt (IPB), is heavily affected by acid mine drainage (AMD), which occurs when pyritic minerals from sulfide mining areas are exposed to atmospheric, hydrological or biological weathering. This paper presents a hydrochemical characterization of parameters in the Odiel River Basin by means of Fuzzy Logic and data mining methodologies to determine the seasonal influence ofAMDin polluted waters that have not been used before for a basin in this environmental area. This technique was proven to be effective, providing results that could not be achieved by using classic statistics, because it allows us to characterize the different parameters separately and also their relationships in waters affected by AMD in a qualitative manner based on the antecedents and according to the conditions (rules) imposed by the consequents (in this case, the Fe(II) and accumulated rainfall over 30 days). Thus, it was possible to confirm that hydrochemistry is greatly affected by seasonal changes, with a higher pH in the wet season (up to 8.59) compared to 2.12, the minimum pH value reached in the dry season. Accordingly, higher concentrations of most of the metals were observed in the dry season (e.g., up to 4000 mg/L of Fe (II)), with the exception of the values found after the first rains that occur in the early fall. With the use of the Fuzzy Logic technique, it was observed that, during the wet season, lixiviates with a higher Fe content have higher metal concentrations, and in the dry season, the behavior is the opposite.