Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic

[EN] The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater-Bi, based on plasticized starch, poly(butylene adipate-co-terephthalate), and poly(epsilon-caprol...

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Authors: Aldas-Carrasco, Miguel Fernando, Arrieta, Marina Patricia, Ferri, J.M|||0000-0002-1269-4973, López-Martínez, Juan|||0000-0001-6904-2282, Samper, María-Dolores|||0000-0002-5102-8412
Format: article
Publication Date:2020
Country:España
Institution:Universitat Politècnica de València (UPV)
Repository:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Language:English
OAI Identifier:oai:riunet.upv.es:10251/151275
Online Access:https://riunet.upv.es/handle/10251/151275
Access Level:Open access
Keyword:Biodegradable polymers
Compatibilizer
Gum rosin
Pine resin derivatives
Plasticizer
Thermoplastic starch
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
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network_acronym_str ES
network_name_str España
repository_id_str
spelling Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplasticAldas-Carrasco, Miguel FernandoArrieta, Marina PatriciaFerri, J.M|||0000-0002-1269-4973López-Martínez, Juan|||0000-0001-6904-2282Samper, María-Dolores|||0000-0002-5102-8412Biodegradable polymersCompatibilizerGum rosinPine resin derivativesPlasticizerThermoplastic starchCIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA[EN] The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater-Bi, based on plasticized starch, poly(butylene adipate-co-terephthalate), and poly(epsilon-caprolactone) (PCL), obtained by injection molding processes, was studied. The mechanical, microstructural, and thermal properties were evaluated. LF had a cohesive behavior with the components of Mater-Bi, increasing the toughness of the material up to 250% accompanied by an increase of tensile modulus and tensile strength. UT had an intermediate behavior, conferring cohesive and plasticizing effects, allowing an increase of 105% in impact resistance. GR had a more marked plasticizing effect. This allows processing temperatures of about 50 degrees C lower than those used for neat Mater-Bi. In addition, an increase of the elongation at break, toughness, and impact resistance in 370, 480, and 250%, respectively, was achieved.This work was supported by the Spanish Ministry of Economy and Competitiveness, PROMADEPCOL (MAT2017-84909-C2-2-R). M. P. Arrieta thanks Complutense University of Madrid for "Ayudas para la contratacion de personal postdoctoral en formacion en docencia e investigacion en departamentos de la UCM."John Wiley & SonsDepartamento de Ingeniería Química y NuclearDepartamento de Ingeniería Mecánica y de Materiales Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyGeneralitat ValencianaAgencia Estatal de InvestigaciónRepositorio Institucional de la Universitat Politècnica de València Riunet20202020-01-20journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/151275reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 MAT2017-84909-C2-2-R PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOSGeneralitat Valenciana https://doi.org/10.13039/501100003359 APOSTD%2F2019%2F122open accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1512752026-06-13T07:49:27Z
dc.title.none.fl_str_mv Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
title Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
spellingShingle Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
Aldas-Carrasco, Miguel Fernando
Biodegradable polymers
Compatibilizer
Gum rosin
Pine resin derivatives
Plasticizer
Thermoplastic starch
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
title_short Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
title_full Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
title_fullStr Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
title_full_unstemmed Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
title_sort Effect of pine resin derivatives on the structural, thermal, and mechanical properties of Mater-Bi type bioplastic
dc.creator.none.fl_str_mv Aldas-Carrasco, Miguel Fernando
Arrieta, Marina Patricia
Ferri, J.M|||0000-0002-1269-4973
López-Martínez, Juan|||0000-0001-6904-2282
Samper, María-Dolores|||0000-0002-5102-8412
author Aldas-Carrasco, Miguel Fernando
author_facet Aldas-Carrasco, Miguel Fernando
Arrieta, Marina Patricia
Ferri, J.M|||0000-0002-1269-4973
López-Martínez, Juan|||0000-0001-6904-2282
Samper, María-Dolores|||0000-0002-5102-8412
author_role author
author2 Arrieta, Marina Patricia
Ferri, J.M|||0000-0002-1269-4973
López-Martínez, Juan|||0000-0001-6904-2282
Samper, María-Dolores|||0000-0002-5102-8412
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Química y Nuclear
Departamento de Ingeniería Mecánica y de Materiales
 Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV
Escuela Politécnica Superior de Alcoy
Generalitat Valenciana
Agencia Estatal de Investigación
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Biodegradable polymers
Compatibilizer
Gum rosin
Pine resin derivatives
Plasticizer
Thermoplastic starch
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
topic Biodegradable polymers
Compatibilizer
Gum rosin
Pine resin derivatives
Plasticizer
Thermoplastic starch
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
description [EN] The effect of three additives derived from pine resin, namely, gum rosin (GR) and two pentaerythritol ester of GR, Lurefor (LF) and Unik Tack (UT), in 5, 10, and 15 wt %, on the properties of Mater-Bi, based on plasticized starch, poly(butylene adipate-co-terephthalate), and poly(epsilon-caprolactone) (PCL), obtained by injection molding processes, was studied. The mechanical, microstructural, and thermal properties were evaluated. LF had a cohesive behavior with the components of Mater-Bi, increasing the toughness of the material up to 250% accompanied by an increase of tensile modulus and tensile strength. UT had an intermediate behavior, conferring cohesive and plasticizing effects, allowing an increase of 105% in impact resistance. GR had a more marked plasticizing effect. This allows processing temperatures of about 50 degrees C lower than those used for neat Mater-Bi. In addition, an increase of the elongation at break, toughness, and impact resistance in 370, 480, and 250%, respectively, was achieved.
publishDate 2020
dc.date.none.fl_str_mv 2020
2020-01-20
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/151275
url https://riunet.upv.es/handle/10251/151275
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 MAT2017-84909-C2-2-R PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS
Generalitat Valenciana https://doi.org/10.13039/501100003359 APOSTD%2F2019%2F122
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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