Structural characterization of the lignins from sugarcane bagasse and straw

The structure of the lignins of sugarcane bagasse and straw was investigated. The lignins were characterized both in situ and in isolated preparations (Milled-Wood Lignin, MWL, and Cellulolytic Lignin, CEL) by Py-GC/MS and 2D-NMR. It was concluded that they are p-hydroxyphenyl-guaiacyl-syringyl lign...

Descripción completa

Detalles Bibliográficos
Autores: Lino, Alessandro Guarino, Rencoret, Jorge, Gutiérrez Suárez, Ana, Colodette, Jorge Luiz, Lima, Claudio F., Martínez, Ángel T., Río Andrade, José Carlos del
Tipo de recurso: otro
Fecha de publicación:2014
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/98709
Acceso en línea:http://hdl.handle.net/10261/98709
Access Level:acceso abierto
Palabra clave:Sugarcane
Bagasse
Straw
Lignin
Py-GC/MS
Py-TMAH
Descripción
Sumario:The structure of the lignins of sugarcane bagasse and straw was investigated. The lignins were characterized both in situ and in isolated preparations (Milled-Wood Lignin, MWL, and Cellulolytic Lignin, CEL) by Py-GC/MS and 2D-NMR. It was concluded that they are p-hydroxyphenyl-guaiacyl-syringyl lignins with associated pcoumarates and ferulates. 2D-NMR indicated that the main substructures present are β–O–4´-ethers, followed by β–5´ phenylcoumarans and with lower amounts of β–β´ resinols and β–1´ spirodienones.