Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

In the title compound, [Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as [mu]-bridges. The coordination of each RhI cation is completed by one cyclo­octa­diene (COD) ligand. It is shown that the average Rh-C(COD) distance is line...

Descripción completa

Detalles Bibliográficos
Autores: Esquius, G., Pons, Josefina, Yáñez, R., Ros, Josep, Solans, Xavier, 1949-2007, Font Bardia, Ma. Mercedes
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2002
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/160142
Acceso en línea:https://hdl.handle.net/2445/160142
Access Level:acceso abierto
Palabra clave:Cristal·lografia
Crystallography
id ES_3df1e187d0001dfd38dc28f4f98642d9
oai_identifier_str oai:diposit.ub.edu:2445/160142
network_acronym_str ES
network_name_str España
repository_id_str
spelling Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvateEsquius, G.Pons, JosefinaYáñez, R.Ros, JosepSolans, Xavier, 1949-2007Font Bardia, Ma. MercedesCristal·lografiaCrystallographyIn the title compound, [Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as [mu]-bridges. The coordination of each RhI cation is completed by one cyclo­octa­diene (COD) ligand. It is shown that the average Rh-C(COD) distance is linearly dependent on the Rh-N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing.International Union of Crystallography2002info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://hdl.handle.net/2445/160142Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésReproducció del document publicat a: https://doi.org/10.1107/S0108270101020017Acta Crystallographica Section C: Crystal Structure Communications, 2002, num. 58, p. m133-m134https://doi.org/10.1107/S0108270101020017(c) International Union of Crystallography, 2002info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1601422026-05-27T06:46:51Z
dc.title.none.fl_str_mv Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
title Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
spellingShingle Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
Esquius, G.
Cristal·lografia
Crystallography
title_short Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
title_full Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
title_fullStr Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
title_full_unstemmed Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
title_sort Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate
dc.creator.none.fl_str_mv Esquius, G.
Pons, Josefina
Yáñez, R.
Ros, Josep
Solans, Xavier, 1949-2007
Font Bardia, Ma. Mercedes
author Esquius, G.
author_facet Esquius, G.
Pons, Josefina
Yáñez, R.
Ros, Josep
Solans, Xavier, 1949-2007
Font Bardia, Ma. Mercedes
author_role author
author2 Pons, Josefina
Yáñez, R.
Ros, Josep
Solans, Xavier, 1949-2007
Font Bardia, Ma. Mercedes
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Cristal·lografia
Crystallography
topic Cristal·lografia
Crystallography
description In the title compound, [Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as [mu]-bridges. The coordination of each RhI cation is completed by one cyclo­octa­diene (COD) ligand. It is shown that the average Rh-C(COD) distance is linearly dependent on the Rh-N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing.
publishDate 2002
dc.date.none.fl_str_mv 2002
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/160142
url https://hdl.handle.net/2445/160142
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1107/S0108270101020017
Acta Crystallographica Section C: Crystal Structure Communications, 2002, num. 58, p. m133-m134
https://doi.org/10.1107/S0108270101020017
dc.rights.none.fl_str_mv (c) International Union of Crystallography, 2002
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) International Union of Crystallography, 2002
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869406479658778624
score 15.300719

Similares en LA Referencia