Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules

Taking advantage of the outstanding properties of a naphthalenediimide-based entangled porous coordination polymer, a simple strategy for the achievement of white light emission is herein presented. The dynamic structural transformation of the [Zn-2(bdc)(2)(dpNDI)](n) metal-organic framework enhance...

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Autores: Sola Llano, Rebeca, Martínez Martínez, Virginia, Furukawa, Shuhei, Takashima, Yohei, López Arbeloa, Iñigo María
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/31985
Acceso en línea:http://hdl.handle.net/10810/31985
Access Level:acceso abierto
Palabra clave:entangled MOF (metal organic framework)
aryl guests
charge transfer
white light emission
CIE (Comission Internationale de l'Eclairage) coordinates
UV illumination
charge-transfer
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spelling Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest MoleculesSola Llano, RebecaMartínez Martínez, VirginiaFurukawa, ShuheiTakashima, YoheiLópez Arbeloa, Iñigo Maríaentangled MOF (metal organic framework)aryl guestscharge transferwhite light emissionCIE (Comission Internationale de l'Eclairage) coordinatesUV illuminationwhite light emissioncharge-transferTaking advantage of the outstanding properties of a naphthalenediimide-based entangled porous coordination polymer, a simple strategy for the achievement of white light emission is herein presented. The dynamic structural transformation of the [Zn-2(bdc)(2)(dpNDI)](n) metal-organic framework enhances the interactions with aryl-guests giving rise to different luminescence colors upon UV (ultraviolet) illumination. Thus, through the rational selection of those small aromatic guest molecules with different electron donor substituents at the appropriate proportion, the emission color was tuned by mixture ratio of guest molecules and even white light emission was achieved. Furthermore, domains in large crystals with a complementary response to linearly polarized light were noticed.This work was funded by the Spanish MINECO (MAT2017-83856-C3-3-P) and from Gobierno Vasco (IT912-16). iCeMS is supported by the World Premier International Research Initiative (WPI), MEXT, Japan.MDPI201920192018info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10810/31985reponame:Addi. Archivo Digital para la Docencia y la Investigacióninstname:Universidad del País VascoInglésinfo:eu-repo/grantAgreement/MINECO/MAT2017-83856-C3-3-P/https://www.mdpi.com/2073-4360/10/2/188info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/3.0/es/This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).Atribución 3.0 Españaoai:addi.ehu.eus:10810/319852026-06-18T09:23:17Z
dc.title.none.fl_str_mv Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
title Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
spellingShingle Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
Sola Llano, Rebeca
entangled MOF (metal organic framework)
aryl guests
charge transfer
white light emission
CIE (Comission Internationale de l'Eclairage) coordinates
UV illumination
white light emission
charge-transfer
title_short Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
title_full Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
title_fullStr Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
title_full_unstemmed Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
title_sort Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
dc.creator.none.fl_str_mv Sola Llano, Rebeca
Martínez Martínez, Virginia
Furukawa, Shuhei
Takashima, Yohei
López Arbeloa, Iñigo María
author Sola Llano, Rebeca
author_facet Sola Llano, Rebeca
Martínez Martínez, Virginia
Furukawa, Shuhei
Takashima, Yohei
López Arbeloa, Iñigo María
author_role author
author2 Martínez Martínez, Virginia
Furukawa, Shuhei
Takashima, Yohei
López Arbeloa, Iñigo María
author2_role author
author
author
author
dc.subject.none.fl_str_mv entangled MOF (metal organic framework)
aryl guests
charge transfer
white light emission
CIE (Comission Internationale de l'Eclairage) coordinates
UV illumination
white light emission
charge-transfer
topic entangled MOF (metal organic framework)
aryl guests
charge transfer
white light emission
CIE (Comission Internationale de l'Eclairage) coordinates
UV illumination
white light emission
charge-transfer
description Taking advantage of the outstanding properties of a naphthalenediimide-based entangled porous coordination polymer, a simple strategy for the achievement of white light emission is herein presented. The dynamic structural transformation of the [Zn-2(bdc)(2)(dpNDI)](n) metal-organic framework enhances the interactions with aryl-guests giving rise to different luminescence colors upon UV (ultraviolet) illumination. Thus, through the rational selection of those small aromatic guest molecules with different electron donor substituents at the appropriate proportion, the emission color was tuned by mixture ratio of guest molecules and even white light emission was achieved. Furthermore, domains in large crystals with a complementary response to linearly polarized light were noticed.
publishDate 2018
dc.date.none.fl_str_mv 2018
2019
2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10810/31985
url http://hdl.handle.net/10810/31985
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/MINECO/MAT2017-83856-C3-3-P/
https://www.mdpi.com/2073-4360/10/2/188
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/3.0/es/
Atribución 3.0 España
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/3.0/es/
Atribución 3.0 España
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:Addi. Archivo Digital para la Docencia y la Investigación
instname:Universidad del País Vasco
instname_str Universidad del País Vasco
reponame_str Addi. Archivo Digital para la Docencia y la Investigación
collection Addi. Archivo Digital para la Docencia y la Investigación
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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