Solvent-free biorefinery of leather fleshing waste into FAMEs and nitrogen-rich co-products

This study presents a solvent-free method for converting bovine and ovine fleshing waste into biodiesel-compatible compounds and a nitrogen-rich solid by-product. The process combines mechanical lipid separation using Tricanter® centrifugation with an optimized alkaline conversion step. Lipid recove...

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Detalles Bibliográficos
Autores: Deroncelé , Víctor, Sorolla, Sílvia, Bacardit i Dalmases, Anna
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Universitat de Lleida (UdL)
Repositorio:Repositori Obert UdL
OAI Identifier:oai:repositori.udl.cat:10459.1/468491
Acceso en línea:https://doi.org/10.1016/j.clet.2025.101065
https://hdl.handle.net/10459.1/468491
Access Level:acceso abierto
Palabra clave:Leather waste
Tricanter® centrifugation
Alkaline transesterification
Circular bioeconomy
Organic fertilizer
Descripción
Sumario:This study presents a solvent-free method for converting bovine and ovine fleshing waste into biodiesel-compatible compounds and a nitrogen-rich solid by-product. The process combines mechanical lipid separation using Tricanter® centrifugation with an optimized alkaline conversion step. Lipid recovery exceeded 92 %, and under optimal reaction conditions, conversion yields surpassed 95 % without the need for pre-treatment. Bovine-derived esters complied with international biodiesel standards, while ovine esters showed promising properties for thermal energy storage applications. The solid fraction, containing up to 9.3 % nitrogen and no regulated heavy metals, met European requirements for use as fertilizer. The process consumed approximately 23 % less energy than conventional methods, and techno-economic analysis supports its industrial feasibility. Overall, this integrated approach offers a scalable, sustainable solution for tannery waste valorization aligned with circular bioeconomy goals.