Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application

The Copahue Thermal Center, situated in Neuquén, Argentina, produces natural and matured peloids, which are employed in the prevention and treatment of various osteoarticular and dermatological disorders. The presence of sulfur as a constituent and its thermotherapeutic potential constitute the prim...

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Autores: Sánchez, Micaela A., Baschini, Miria T., Pozo Rodríguez, Manuel, Gramisci, Betina R., Roca Jalil, María E., Vela, María L.
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/714153
Acceso en línea:http://hdl.handle.net/10486/714153
https://dx.doi.org/10.3390/ma16145062
Access Level:acceso abierto
Palabra clave:Dry peloids
mudpack
paraffin
thermotherapy
Geología
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spelling Paraffin–Peloid Formulations from Copahue: Processing, Characterization and ApplicationSánchez, Micaela A.Baschini, Miria T.Pozo Rodríguez, ManuelGramisci, Betina R.Roca Jalil, María E.Vela, María L.Dry peloidsmudpackparaffinthermotherapyGeologíaThe Copahue Thermal Center, situated in Neuquén, Argentina, produces natural and matured peloids, which are employed in the prevention and treatment of various osteoarticular and dermatological disorders. The presence of sulfur as a constituent and its thermotherapeutic potential constitute the primary strengths of these peloids. Nevertheless, accessing Copahue is challenging due to its distance from densely populated centers and the snow cover during the winter months in the southern hemisphere. Therefore, in order to propose a material that can be utilized year-round in any location, a mudpack was obtained by combining medicinal paraffin with dehydrated Copahue peloids, with concentrations evaluated up to 10% w/w. This mudpack was analyzed through X-ray diffraction, which detected the presence of sulfur, the most important component of Copahue’s peloids. Through IR spectroscopy, the signals that identify medicinal paraffin were clearly observed, and for concentrations of 6% and 10% peloid in the material, it was possible to detect the presence of mineral clay components associated with Si-O stretching vibrations at around 1041 cm−1. The low values of luminosity and grey tonality obtained for the mudpack contributed to patient acceptability and the absorption of electromagnetic radiation. The experimental cooling rate, calculated using the ratio of the temperature variation (∆T) with respect to the time variation (∆t) in each interval of the experimental curve, was determined to be 0.6 °C·min−1 for both paraffin and the mudpack. However, for peloids, higher values ranging from 0.6 to 4.8 °C·min−1 were obtained. This suggests that the mudpack mixtures have a slower heat release, which is a desirable property for their use as a thermotherapeutic agent. Considering the reusability of the mudpack, its stability was evaluated after 10 cycles of cooling and heating through XRD, DSC, and FTIR tests, resulting in a system that retains its properties. The formulation of the obtained mudpack is promising for the development of these materials on a larger scaleThis research was supported by the National University of Comahue, through project 04–I249: “Materiales adsorbentes naturales y modificados aplicados en termalismo”Multidisciplinary Digital Publishing Institute (MDPI)Departamento de Geología y GeoquímicaFacultad de Ciencias20232023-07-18research articlehttp://purl.org/coar/resource_type/c_2df8fbb1VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/714153https://dx.doi.org/10.3390/ma16145062reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/7141532026-06-23T12:46:27Z
dc.title.none.fl_str_mv Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
title Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
spellingShingle Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
Sánchez, Micaela A.
Dry peloids
mudpack
paraffin
thermotherapy
Geología
title_short Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
title_full Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
title_fullStr Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
title_full_unstemmed Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
title_sort Paraffin–Peloid Formulations from Copahue: Processing, Characterization and Application
dc.creator.none.fl_str_mv Sánchez, Micaela A.
Baschini, Miria T.
Pozo Rodríguez, Manuel
Gramisci, Betina R.
Roca Jalil, María E.
Vela, María L.
author Sánchez, Micaela A.
author_facet Sánchez, Micaela A.
Baschini, Miria T.
Pozo Rodríguez, Manuel
Gramisci, Betina R.
Roca Jalil, María E.
Vela, María L.
author_role author
author2 Baschini, Miria T.
Pozo Rodríguez, Manuel
Gramisci, Betina R.
Roca Jalil, María E.
Vela, María L.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Geología y Geoquímica
Facultad de Ciencias
dc.subject.none.fl_str_mv Dry peloids
mudpack
paraffin
thermotherapy
Geología
topic Dry peloids
mudpack
paraffin
thermotherapy
Geología
description The Copahue Thermal Center, situated in Neuquén, Argentina, produces natural and matured peloids, which are employed in the prevention and treatment of various osteoarticular and dermatological disorders. The presence of sulfur as a constituent and its thermotherapeutic potential constitute the primary strengths of these peloids. Nevertheless, accessing Copahue is challenging due to its distance from densely populated centers and the snow cover during the winter months in the southern hemisphere. Therefore, in order to propose a material that can be utilized year-round in any location, a mudpack was obtained by combining medicinal paraffin with dehydrated Copahue peloids, with concentrations evaluated up to 10% w/w. This mudpack was analyzed through X-ray diffraction, which detected the presence of sulfur, the most important component of Copahue’s peloids. Through IR spectroscopy, the signals that identify medicinal paraffin were clearly observed, and for concentrations of 6% and 10% peloid in the material, it was possible to detect the presence of mineral clay components associated with Si-O stretching vibrations at around 1041 cm−1. The low values of luminosity and grey tonality obtained for the mudpack contributed to patient acceptability and the absorption of electromagnetic radiation. The experimental cooling rate, calculated using the ratio of the temperature variation (∆T) with respect to the time variation (∆t) in each interval of the experimental curve, was determined to be 0.6 °C·min−1 for both paraffin and the mudpack. However, for peloids, higher values ranging from 0.6 to 4.8 °C·min−1 were obtained. This suggests that the mudpack mixtures have a slower heat release, which is a desirable property for their use as a thermotherapeutic agent. Considering the reusability of the mudpack, its stability was evaluated after 10 cycles of cooling and heating through XRD, DSC, and FTIR tests, resulting in a system that retains its properties. The formulation of the obtained mudpack is promising for the development of these materials on a larger scale
publishDate 2023
dc.date.none.fl_str_mv 2023
2023-07-18
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/714153
https://dx.doi.org/10.3390/ma16145062
url http://hdl.handle.net/10486/714153
https://dx.doi.org/10.3390/ma16145062
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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