Laser induced nanostructuration of vertically aligned carbon nanotubes coated with nickel oxide nanoparticles

A facile method is explored to decorate vertically aligned multi-walled carbon nanotubes (VACNTs) with NiO nanostructures. Multi-walled VACNTs are grown by plasma enhanced chemical vapor deposition and coated with NiO nanoparticles (NPs) by drop casting and submitted to pulsed UV laser irradiation....

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Detalles Bibliográficos
Autores: Pérez del Pino, Ángel, György, Eniko, Hussain, Shahzad, Andújar Bella, José Luis, Pascual Miralles, Esther, Amade Rovira, Roger, Bertrán Serra, Enric
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/128190
Acceso en línea:https://hdl.handle.net/2445/128190
Access Level:acceso abierto
Palabra clave:Nanopartícules
Nanotubs
Condensadors elèctrics
Làsers
Nanoparticles
Nanotubes
Capacitors
Lasers
Descripción
Sumario:A facile method is explored to decorate vertically aligned multi-walled carbon nanotubes (VACNTs) with NiO nanostructures. Multi-walled VACNTs are grown by plasma enhanced chemical vapor deposition and coated with NiO nanoparticles (NPs) by drop casting and submitted to pulsed UV laser irradiation. Laser irradiation provokes rapid heating-melting-cooling processes which lead to the recrystallization of NiO NPs on the outer walls of VACNTs'. In this way, and depending on the laser fluence and the number of accumulated pulses, different nano-architectures such as continuous NiO coatings and spiny features are obtained. High resolution scanning and transmission electron microscopies and Raman spectroscopy, corroborated with photothermal simulations, suggest that the grown nanostructures are mainly created by the laser-induced high temperatures and catalytic action of NiO NPs.