A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate

Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, high...

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Detalles Bibliográficos
Autores: Li, Jian, Gao, Zihao Rei, Lin, Qing-Fang, Liu, Chenxu, Gao, Fangxin, Lin, Cong, Zhang, Siyao, Deng, Hua, Mayoral, Alvaro, Fan, Wei, Luo, Song, Chen, Xiaobo, He, Hong, Camblor, Miguel A., Chen, Fei-Jian, Yu, Jihong
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2023
País:España
Institución:Universidad de Zaragoza
Repositorio:Zaguán. Repositorio Digital de la Universidad de Zaragoza
OAI Identifier:oai:zaguan.unizar.es:124026
Acceso en línea:http://zaguan.unizar.es/record/124026
Access Level:acceso abierto
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spelling A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicateLi, JianGao, Zihao ReiLin, Qing-FangLiu, ChenxuGao, FangxinLin, CongZhang, SiyaoDeng, HuaMayoral, AlvaroFan, WeiLuo, SongChen, XiaoboHe, HongCamblor, Miguel A.Chen, Fei-JianYu, JihongZeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.2023info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://zaguan.unizar.es/record/124026reponame:Zaguán. Repositorio Digital de la Universidad de Zaragozainstname:Universidad de ZaragozaInglésinfo:eu-repo/semantics/openAccessoai:zaguan.unizar.es:1240262026-05-29T13:59:51Z
dc.title.none.fl_str_mv A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
title A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
spellingShingle A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
Li, Jian
title_short A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
title_full A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
title_fullStr A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
title_full_unstemmed A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
title_sort A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
dc.creator.none.fl_str_mv Li, Jian
Gao, Zihao Rei
Lin, Qing-Fang
Liu, Chenxu
Gao, Fangxin
Lin, Cong
Zhang, Siyao
Deng, Hua
Mayoral, Alvaro
Fan, Wei
Luo, Song
Chen, Xiaobo
He, Hong
Camblor, Miguel A.
Chen, Fei-Jian
Yu, Jihong
author Li, Jian
author_facet Li, Jian
Gao, Zihao Rei
Lin, Qing-Fang
Liu, Chenxu
Gao, Fangxin
Lin, Cong
Zhang, Siyao
Deng, Hua
Mayoral, Alvaro
Fan, Wei
Luo, Song
Chen, Xiaobo
He, Hong
Camblor, Miguel A.
Chen, Fei-Jian
Yu, Jihong
author_role author
author2 Gao, Zihao Rei
Lin, Qing-Fang
Liu, Chenxu
Gao, Fangxin
Lin, Cong
Zhang, Siyao
Deng, Hua
Mayoral, Alvaro
Fan, Wei
Luo, Song
Chen, Xiaobo
He, Hong
Camblor, Miguel A.
Chen, Fei-Jian
Yu, Jihong
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
description Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.
publishDate 2023
dc.date.none.fl_str_mv 2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://zaguan.unizar.es/record/124026
url http://zaguan.unizar.es/record/124026
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv
publisher.none.fl_str_mv
dc.source.none.fl_str_mv reponame:Zaguán. Repositorio Digital de la Universidad de Zaragoza
instname:Universidad de Zaragoza
instname_str Universidad de Zaragoza
reponame_str Zaguán. Repositorio Digital de la Universidad de Zaragoza
collection Zaguán. Repositorio Digital de la Universidad de Zaragoza
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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