New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane
X-ray diffraction analyses of the pure components n-tricosane and n-pentacosane and of their binary mixed samples have enabled us to characterize the crystalline phases observed at low temperature. On the contrary to what was announced in literature on the structural behavior of mixed samples in odd...
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1999 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/18201 |
| Acceso en línea: | https://hdl.handle.net/2445/18201 |
| Access Level: | acceso abierto |
| Palabra clave: | Alcans Difracció de raigs X Alkanes X-rays diffraction |
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New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosaneRajabalee, Fazil AhmadMetivaud, ValérieMondieig, Denise, 1958-Haget, YvetteCuevas Diarte, Miguel ÁngelAlcansDifracció de raigs XAlkanesX-rays diffractionX-ray diffraction analyses of the pure components n-tricosane and n-pentacosane and of their binary mixed samples have enabled us to characterize the crystalline phases observed at low temperature. On the contrary to what was announced in literature on the structural behavior of mixed samples in odd-odd binary systems with D n = 2, the three domains are not all orthorhombic. This work has enabled us to show that two of the domains are, in fact, monoclinic, (Aa, Z = 4) and the other one is orthorhombic (Pca21, Z = 4). The conclusions drawn in this work can be easily transposed to other binary systems of n-alkanes.Materials Research Society201120111999info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion11 p.application/pdfhttps://hdl.handle.net/2445/18201Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció document publicat a: http://dx.doi.org/10.1557/JMR.1999.0354Journal of Materials Research, 1999, vol. 14, núm. 6, p. 2644-2654http://dx.doi.org/10.1557/JMR.1999.0354(c) Materials Research Society, 1999info:eu-repo/semantics/openAccessoai:recercat.cat:2445/182012026-05-29T05:05:01Z |
| dc.title.none.fl_str_mv |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane |
| title |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane |
| spellingShingle |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane Rajabalee, Fazil Ahmad Alcans Difracció de raigs X Alkanes X-rays diffraction |
| title_short |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane |
| title_full |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane |
| title_fullStr |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane |
| title_full_unstemmed |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane |
| title_sort |
New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane |
| dc.creator.none.fl_str_mv |
Rajabalee, Fazil Ahmad Metivaud, Valérie Mondieig, Denise, 1958- Haget, Yvette Cuevas Diarte, Miguel Ángel |
| author |
Rajabalee, Fazil Ahmad |
| author_facet |
Rajabalee, Fazil Ahmad Metivaud, Valérie Mondieig, Denise, 1958- Haget, Yvette Cuevas Diarte, Miguel Ángel |
| author_role |
author |
| author2 |
Metivaud, Valérie Mondieig, Denise, 1958- Haget, Yvette Cuevas Diarte, Miguel Ángel |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Alcans Difracció de raigs X Alkanes X-rays diffraction |
| topic |
Alcans Difracció de raigs X Alkanes X-rays diffraction |
| description |
X-ray diffraction analyses of the pure components n-tricosane and n-pentacosane and of their binary mixed samples have enabled us to characterize the crystalline phases observed at low temperature. On the contrary to what was announced in literature on the structural behavior of mixed samples in odd-odd binary systems with D n = 2, the three domains are not all orthorhombic. This work has enabled us to show that two of the domains are, in fact, monoclinic, (Aa, Z = 4) and the other one is orthorhombic (Pca21, Z = 4). The conclusions drawn in this work can be easily transposed to other binary systems of n-alkanes. |
| publishDate |
1999 |
| dc.date.none.fl_str_mv |
1999 2011 2011 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
https://hdl.handle.net/2445/18201 |
| url |
https://hdl.handle.net/2445/18201 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
Reproducció document publicat a: http://dx.doi.org/10.1557/JMR.1999.0354 Journal of Materials Research, 1999, vol. 14, núm. 6, p. 2644-2654 http://dx.doi.org/10.1557/JMR.1999.0354 |
| dc.rights.none.fl_str_mv |
(c) Materials Research Society, 1999 info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
(c) Materials Research Society, 1999 |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
11 p. application/pdf |
| dc.publisher.none.fl_str_mv |
Materials Research Society |
| publisher.none.fl_str_mv |
Materials Research Society |
| dc.source.none.fl_str_mv |
Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) reponame:Recercat. Dipósit de la Recerca de Catalunya instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
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Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| reponame_str |
Recercat. Dipósit de la Recerca de Catalunya |
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Recercat. Dipósit de la Recerca de Catalunya |
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1869406219471421440 |
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15.812429 |