Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review

In this paper, the lanthanoid complexes of N5 and N6 macrocycle ligands, without pendant arms or additional heteroatoms, are surveyed. This review covers the period from 2015 to the current date, since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety, and their complexes, we...

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Detalhes bibliográficos
Autores: Corredoira Vázquez, Julio, González-Barreira, Cristina, Oreiro-Martínez, Paula, García Deibe, Ana María, Sanmartín Matalobos, Jesús, Fondo Busto, María Matilde
Formato: artículo
Fecha de publicación:2024
País:España
Recursos:Universidad de Santiago de Compostela (USC)
Repositorio:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Idioma:inglés
OAI Identifier:oai:minerva.usc.gal:10347/32219
Acesso em linha:http://hdl.handle.net/10347/32219
Access Level:acceso abierto
Palavra-chave:2303 Química inorgánica
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spelling Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A reviewCorredoira Vázquez, JulioGonzález-Barreira, CristinaOreiro-Martínez, PaulaGarcía Deibe, Ana MaríaSanmartín Matalobos, JesúsFondo Busto, María Matilde2303 Química inorgánicaIn this paper, the lanthanoid complexes of N5 and N6 macrocycle ligands, without pendant arms or additional heteroatoms, are surveyed. This review covers the period from 2015 to the current date, since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety, and their complexes, were revised, and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also summarized. Porphyrin and phthalocyanine ligands are not included in this review, which primarily focuses on complexes with Schiff bases and amines without pendant arms or any additional donor other than nitrogen. The synthetic methods, structural characterization, based on single X-ray crystal data, and properties of the lanthanoid complexes, with special attention to magneto-structural correlations, are presented herein.ElsevierUniversidade de Santiago de Compostela. Departamento de Química Inorgánica20242024-01-0120242024-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10347/32219reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostelainstname:Universidad de Santiago de Compostela (USC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:minerva.usc.gal:10347/322192026-06-15T12:47:27Z
dc.title.none.fl_str_mv Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
title Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
spellingShingle Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
Corredoira Vázquez, Julio
2303 Química inorgánica
title_short Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
title_full Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
title_fullStr Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
title_full_unstemmed Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
title_sort Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
dc.creator.none.fl_str_mv Corredoira Vázquez, Julio
González-Barreira, Cristina
Oreiro-Martínez, Paula
García Deibe, Ana María
Sanmartín Matalobos, Jesús
Fondo Busto, María Matilde
author Corredoira Vázquez, Julio
author_facet Corredoira Vázquez, Julio
González-Barreira, Cristina
Oreiro-Martínez, Paula
García Deibe, Ana María
Sanmartín Matalobos, Jesús
Fondo Busto, María Matilde
author_role author
author2 González-Barreira, Cristina
Oreiro-Martínez, Paula
García Deibe, Ana María
Sanmartín Matalobos, Jesús
Fondo Busto, María Matilde
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade de Santiago de Compostela. Departamento de Química Inorgánica
dc.subject.none.fl_str_mv 2303 Química inorgánica
topic 2303 Química inorgánica
description In this paper, the lanthanoid complexes of N5 and N6 macrocycle ligands, without pendant arms or additional heteroatoms, are surveyed. This review covers the period from 2015 to the current date, since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety, and their complexes, were revised, and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also summarized. Porphyrin and phthalocyanine ligands are not included in this review, which primarily focuses on complexes with Schiff bases and amines without pendant arms or any additional donor other than nitrogen. The synthetic methods, structural characterization, based on single X-ray crystal data, and properties of the lanthanoid complexes, with special attention to magneto-structural correlations, are presented herein.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-01-01
2024
2024-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10347/32219
url http://hdl.handle.net/10347/32219
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
instname:Universidad de Santiago de Compostela (USC)
instname_str Universidad de Santiago de Compostela (USC)
reponame_str Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
collection Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
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repository.mail.fl_str_mv
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