Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride

Life cycle analysis and exergy analysis are applied to compare the production of maleic anhydride from different feedstock, both biomass- and petrochemical-derived raw materials, in order to evaluate the sustainability of alternative biorefinery processes to conventional routes. The considered proce...

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Detalles Bibliográficos
Autores: Blanco, Jorge, Millán-Linares, María del Carmen, López Granados, Manuel, Agirre, Ion, Gandarias, Iñaki, Arias, Pedro Luis, Iglesias, Jose, Moreno, Jovita, Sánchez-García, Alicia
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/416167
Acceso en línea:http://hdl.handle.net/10261/416167
https://api.elsevier.com/content/abstract/scopus_id/85132321669
Access Level:acceso abierto
Palabra clave:environmental impacts
exergoeconomic analysis
furfural
life cycle analysis
maleic anhydride
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spelling Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic AnhydrideBlanco, JorgeMillán-Linares, María del CarmenLópez Granados, ManuelAgirre, IonGandarias, IñakiArias, Pedro LuisIglesias, JoseMoreno, JovitaSánchez-García, Aliciaenvironmental impactsexergoeconomic analysisfurfurallife cycle analysismaleic anhydrideLife cycle analysis and exergy analysis are applied to compare the production of maleic anhydride from different feedstock, both biomass- and petrochemical-derived raw materials, in order to evaluate the sustainability of alternative biorefinery processes to conventional routes. The considered processes involve two options: gas and aqueous phase furfural oxidation with oxygen (air) and hydrogen peroxide as oxidants, respectively, considered as sustainable technologies because of the use of renewable feedstock. Conventional routes, used as benchmarks, include the current production processes using benzene or butane as raw materials. The results show that the aqueous phase process is far from being viable from an energy and environmental point of view due to the high exergy destruction and the use of H<inf>2</inf>O<inf>2</inf> as oxidant (whose production entails important environmental drawbacks). On the contrary, the gas phase oxidation of furfural shows competitive results with petrochemical technologies. Nevertheless, the major environmental drawback of the new furfural-to-maleic anhydride production processes is detected on the environmental profile of the starting raw material. The results suggest that a better environmental footprint for maleic anhydride production in gas phase can be obtained if environmentally friendly furfural production technologies are used at the commercial scale.This research was funded by the Spanish Ministry of Science, Innovationand Universities (projects RTI2018-094918-B-C41, RTI2018-094918-B-C42,and RTI2018-094918-B-C43).Peer reviewedWiley-VCHMinisterio de Ciencia, Innovación y Universidades (España)Agencia Estatal de Investigación (España)0000-0002-5451-90220000-0002-5561-286X0000-0002-1269-06220000-0003-4546-539X0000-0002-4082-53520000-0002-6239-02300000-0001-5929-26080000-0001-7614-40250000-0002-8221-0161Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202620262022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/416167https://api.elsevier.com/content/abstract/scopus_id/85132321669reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-094918-B-C41info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-094918-B-C42info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-094918-B-C43Advanced Sustainable Systemshttps://doi.org/10.1002/adsu.202200121Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/4161672026-05-22T06:33:51Z
dc.title.none.fl_str_mv Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
title Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
spellingShingle Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
Blanco, Jorge
environmental impacts
exergoeconomic analysis
furfural
life cycle analysis
maleic anhydride
title_short Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
title_full Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
title_fullStr Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
title_full_unstemmed Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
title_sort Integrated Environmental and Exergoeconomic Analysis of Biomass-Derived Maleic Anhydride
dc.creator.none.fl_str_mv Blanco, Jorge
Millán-Linares, María del Carmen
López Granados, Manuel
Agirre, Ion
Gandarias, Iñaki
Arias, Pedro Luis
Iglesias, Jose
Moreno, Jovita
Sánchez-García, Alicia
author Blanco, Jorge
author_facet Blanco, Jorge
Millán-Linares, María del Carmen
López Granados, Manuel
Agirre, Ion
Gandarias, Iñaki
Arias, Pedro Luis
Iglesias, Jose
Moreno, Jovita
Sánchez-García, Alicia
author_role author
author2 Millán-Linares, María del Carmen
López Granados, Manuel
Agirre, Ion
Gandarias, Iñaki
Arias, Pedro Luis
Iglesias, Jose
Moreno, Jovita
Sánchez-García, Alicia
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia, Innovación y Universidades (España)
Agencia Estatal de Investigación (España)
0000-0002-5451-9022
0000-0002-5561-286X
0000-0002-1269-0622
0000-0003-4546-539X
0000-0002-4082-5352
0000-0002-6239-0230
0000-0001-5929-2608
0000-0001-7614-4025
0000-0002-8221-0161
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv environmental impacts
exergoeconomic analysis
furfural
life cycle analysis
maleic anhydride
topic environmental impacts
exergoeconomic analysis
furfural
life cycle analysis
maleic anhydride
description Life cycle analysis and exergy analysis are applied to compare the production of maleic anhydride from different feedstock, both biomass- and petrochemical-derived raw materials, in order to evaluate the sustainability of alternative biorefinery processes to conventional routes. The considered processes involve two options: gas and aqueous phase furfural oxidation with oxygen (air) and hydrogen peroxide as oxidants, respectively, considered as sustainable technologies because of the use of renewable feedstock. Conventional routes, used as benchmarks, include the current production processes using benzene or butane as raw materials. The results show that the aqueous phase process is far from being viable from an energy and environmental point of view due to the high exergy destruction and the use of H<inf>2</inf>O<inf>2</inf> as oxidant (whose production entails important environmental drawbacks). On the contrary, the gas phase oxidation of furfural shows competitive results with petrochemical technologies. Nevertheless, the major environmental drawback of the new furfural-to-maleic anhydride production processes is detected on the environmental profile of the starting raw material. The results suggest that a better environmental footprint for maleic anhydride production in gas phase can be obtained if environmentally friendly furfural production technologies are used at the commercial scale.
publishDate 2022
dc.date.none.fl_str_mv 2022
2026
2026
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/416167
https://api.elsevier.com/content/abstract/scopus_id/85132321669
url http://hdl.handle.net/10261/416167
https://api.elsevier.com/content/abstract/scopus_id/85132321669
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-094918-B-C41
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-094918-B-C42
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-094918-B-C43
Advanced Sustainable Systems
https://doi.org/10.1002/adsu.202200121
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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