Enhancement of Metal-Organic Frameworks properties by the association of active nano-species
Metal-Organic Frameworks (MOFs) are crystalline solids composed by inorganic units (atoms, clusters, chains, …) linked by ionocovalent bonds to organic polydentate ligands (carboxylates, phosphonates, azolates, …) procuring a highly porous three-dimensional (3D) network. From the first reports in th...
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| Formato: | tesis doctoral |
| Fecha de publicación: | 2022 |
| País: | España |
| Recursos: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/3435 |
| Acesso em linha: | https://hdl.handle.net/20.500.14352/3435 |
| Access Level: | acceso abierto |
| Palavra-chave: | 546(043.2) Chemistry Inorganic Química inorgánica Química inorgánica (Química) 2303 Química Inorgánica |
| Resumo: | Metal-Organic Frameworks (MOFs) are crystalline solids composed by inorganic units (atoms, clusters, chains, …) linked by ionocovalent bonds to organic polydentate ligands (carboxylates, phosphonates, azolates, …) procuring a highly porous three-dimensional (3D) network. From the first reports in the early 90s, interest in MOFs, their chemistry and their applications have increased exponentially. Proving so, are the >13,300 publications registered only in 2020 (Web-of-Science: “Metal-Organic Frameworks”). MOFs outstand from other porous materials due to their hybrid versatile organic-inorganic composition (tunable ligands, presence of unsaturated metallic centers…), their structural richness (multiple topologies, isoreticular families…) and their exceptional porosity (with specific surface areas-SBET up to 8000 m2·g-1). As consequence, they have become an ideal candidate for relevant industrial and societal applications... |
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