Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework

The oxidation of biomass-derived compounds such as glucose within electrochemical cells enables both the energy-efficient production of hydrogen and the generation of additional added-value chemicals from biomass. However, for this biomass valorization approach to become commercially viable, selecti...

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Autores: Mejia Centeno, Karol V., Montaña Mora, Guillem, Chacón Borrero, Jesús, Xue, Qian, Martí-Sánchez, Sara, Berlanga Vázquez, Armando, Llorca Piqué, Jordi|||0000-0002-7447-9582, Arbiol Cobos, Jordi, Qi, Xueqiang, Martinez Alanis, Paulina Raquel, Cabot, Andreu
Formato: artículo
Fecha de publicación:2025
País:España
Recursos:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:dnet:upcommonspor::650da5c7d495a01ea3ab39943395d378
Acesso em linha:https://hdl.handle.net/2117/459960
https://dx.doi.org/10.1016/j.cej.2025.163491
Access Level:acceso embargado
Palavra-chave:Glucose oxidation
Zeolitic imidazole framework
Hydrogen
Formic acid
Electrochemical biomass valorization
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dc.title.none.fl_str_mv Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
title Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
spellingShingle Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
Mejia Centeno, Karol V.
Glucose oxidation
Zeolitic imidazole framework
Hydrogen
Formic acid
Electrochemical biomass valorization
title_short Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
title_full Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
title_fullStr Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
title_full_unstemmed Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
title_sort Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework
dc.creator.none.fl_str_mv Mejia Centeno, Karol V.
Montaña Mora, Guillem
Chacón Borrero, Jesús
Xue, Qian
Martí-Sánchez, Sara
Berlanga Vázquez, Armando
Llorca Piqué, Jordi|||0000-0002-7447-9582
Arbiol Cobos, Jordi
Qi, Xueqiang
Martinez Alanis, Paulina Raquel
Cabot, Andreu
author Mejia Centeno, Karol V.
author_facet Mejia Centeno, Karol V.
Montaña Mora, Guillem
Chacón Borrero, Jesús
Xue, Qian
Martí-Sánchez, Sara
Berlanga Vázquez, Armando
Llorca Piqué, Jordi|||0000-0002-7447-9582
Arbiol Cobos, Jordi
Qi, Xueqiang
Martinez Alanis, Paulina Raquel
Cabot, Andreu
author_role author
author2 Montaña Mora, Guillem
Chacón Borrero, Jesús
Xue, Qian
Martí-Sánchez, Sara
Berlanga Vázquez, Armando
Llorca Piqué, Jordi|||0000-0002-7447-9582
Arbiol Cobos, Jordi
Qi, Xueqiang
Martinez Alanis, Paulina Raquel
Cabot, Andreu
author2_role author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Glucose oxidation
Zeolitic imidazole framework
Hydrogen
Formic acid
Electrochemical biomass valorization
topic Glucose oxidation
Zeolitic imidazole framework
Hydrogen
Formic acid
Electrochemical biomass valorization
description The oxidation of biomass-derived compounds such as glucose within electrochemical cells enables both the energy-efficient production of hydrogen and the generation of additional added-value chemicals from biomass. However, for this biomass valorization approach to become commercially viable, selective, cost-effective, and highly active electrooxidation catalysts need to be developed. In this work, we detail the synthesis of a nickel (Ni) and zinc (Zn)-based electrocatalyst for the glucose oxidation reaction (GOR) to formic acid (FoA) via calcination of a Zn-based zeolitic imidazole framework (ZIF) functionalized with ethylenediamine and doped with Ni. The structure, morphology, and electrochemical performance of the catalysts towards the anodic GOR to FoA coupled with the cathodic hydrogen evolution reaction (HER) are subsequently studied. Chronopotentiometry tests with 0.1 M of glucose show a conversion of 94 % at 250 mA in only 70 minutes, with a Faradaic efficiency (FE) of 91 % toward the production of FoA. Meanwhile, at the cathode, the HER FE is close to 98 %.
publishDate 2025
dc.date.none.fl_str_mv 2025
2025-07-01
2026
2026-03-27
2027
2027-07-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/459960
https://dx.doi.org/10.1016/j.cej.2025.163491
url https://hdl.handle.net/2117/459960
https://dx.doi.org/10.1016/j.cej.2025.163491
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2022-136883OB-C22 PROCESOS CATALITICOS DUALES SINERGICOS
Agencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2023-149158OB-C43 METODOS DE CARACTERIZACION BASADOS EN MICROSCOPIA ELECTRONICA AVANZADA PARA MATERIALES Y DISPOSITIVOS PARA LA ENERGIA
Agencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-124572OB-C31 TECNOLOGIAS ENERGETICAS DEL HIDROGENO IMPULSADAS POR INGENIERIA DE INTERFAZ DE CATALIZADORES AMORFOS%2FCRISTALINOS
dc.rights.none.fl_str_mv embargoed access
http://purl.org/coar/access_right/c_f1cf
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/embargoedAccess
rights_invalid_str_mv embargoed access
http://purl.org/coar/access_right/c_f1cf
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
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dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
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spelling Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole frameworkMejia Centeno, Karol V.Montaña Mora, GuillemChacón Borrero, JesúsXue, QianMartí-Sánchez, SaraBerlanga Vázquez, ArmandoLlorca Piqué, Jordi|||0000-0002-7447-9582Arbiol Cobos, JordiQi, XueqiangMartinez Alanis, Paulina RaquelCabot, AndreuGlucose oxidationZeolitic imidazole frameworkHydrogenFormic acidElectrochemical biomass valorizationThe oxidation of biomass-derived compounds such as glucose within electrochemical cells enables both the energy-efficient production of hydrogen and the generation of additional added-value chemicals from biomass. However, for this biomass valorization approach to become commercially viable, selective, cost-effective, and highly active electrooxidation catalysts need to be developed. In this work, we detail the synthesis of a nickel (Ni) and zinc (Zn)-based electrocatalyst for the glucose oxidation reaction (GOR) to formic acid (FoA) via calcination of a Zn-based zeolitic imidazole framework (ZIF) functionalized with ethylenediamine and doped with Ni. The structure, morphology, and electrochemical performance of the catalysts towards the anodic GOR to FoA coupled with the cathodic hydrogen evolution reaction (HER) are subsequently studied. Chronopotentiometry tests with 0.1 M of glucose show a conversion of 94 % at 250 mA in only 70 minutes, with a Faradaic efficiency (FE) of 91 % toward the production of FoA. Meanwhile, at the cathode, the HER FE is close to 98 %.This work was financially supported by the SyDECat and AmaDE projects from the Spanish MCIN/AEI/FEDER (PID2022-136883OB-C22 & PID2023-149158OB-C43). The authors acknowledge funding from Generalitat de Catalunya 2021SGR01581, 2021SGR00457 and Euro pean Union Next Generation EU/PRTR. KVMC acknowledges the grant from Call 906 of 2021 for Doctorates Abroad from the Ministry of ence, Technology, and Innovation of Colombia. PRMA acknowledges support from the Ramón y Cajal grant RYC2023-042982-I, funded by MICIU/AEI (10.13039/501100011033) and co-financed by FSE+. This study is part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR- C17.I1) and by Generalitat de Catalunya (In-CAEM Project). ICN2 is supported by the Severo Ochoa program from Spanish MCIN / AEI (Grant No.: CEX2021-001214-S) and is funded by the CERCA gramme / Generalitat de Catalunya. ICN2 is founding member of e- DREAM. [76] J.L. is a Serra Húnter Fellow and is grateful to the ICREA Academia program and to projects PID2021-124572OB-C31 and CEX2023-001300-M funded by MCIN/AEI/10.13039/501100011033, EU and FEDER, and to the GC 2021 SGR 01061 grant.7 - Energia Assequible i No Contaminant13 - Acció per al ClimaElsevier20252025-07-0120262026-03-2720272027-07-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/459960https://dx.doi.org/10.1016/j.cej.2025.163491reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)InglésengAgencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2022-136883OB-C22 PROCESOS CATALITICOS DUALES SINERGICOSAgencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2023-149158OB-C43 METODOS DE CARACTERIZACION BASADOS EN MICROSCOPIA ELECTRONICA AVANZADA PARA MATERIALES Y DISPOSITIVOS PARA LA ENERGIAAgencia Estatal de Investigación http://doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-124572OB-C31 TECNOLOGIAS ENERGETICAS DEL HIDROGENO IMPULSADAS POR INGENIERIA DE INTERFAZ DE CATALIZADORES AMORFOS%2FCRISTALINOSembargoed accesshttp://purl.org/coar/access_right/c_f1cfAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccessoai:dnet:upcommonspor::650da5c7d495a01ea3ab39943395d3782026-05-27T15:37:01Z
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