Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants
Línea Investigación: Línea 1. Procesos de depuración de aguas residuales
| Autores: | , , , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2013 |
| País: | España |
| Institución: | Universidad Rey Juan Carlos |
| Repositorio: | BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos |
| OAI Identifier: | oai:burjcdigital.urjc.es:10115/11836 |
| Acceso en línea: | http://hdl.handle.net/10115/11836 |
| Access Level: | acceso abierto |
| Palabra clave: | Medio Ambiente Pharmaceutical Pollutants Nanofiltration Reverse Osmosis Photocatalysis Photo-Fenton 2391 Química Ambiental |
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España |
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Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutantsMartínez, F.López-Muñoz, M.J.Aguado, J.Melero, J.A.Arsuaga, J.Sotto, A.Molina, R.Segura, Y.Pariente, M.I.Revilla, A.Cerro, L.Carenas, G.Medio AmbientePharmaceutical PollutantsNanofiltrationReverse OsmosisPhotocatalysisPhoto-Fenton2391 Química AmbientalLínea Investigación: Línea 1. Procesos de depuración de aguas residualesThe coupling of membrane separation and photocatalytic oxidation has been studied for the removal of pharmaceutical pollutants. The retention properties of two different membranes (nanofiltration and reverse osmosis) were assessed. Comparable selectivity on the separation of pharmaceuticals were observed for both membranes, obtaining a permeate stream with concentrations of each pharmaceutical below 0.5 mg/L and a rejected flux highly concentrated (in the range of 16-25 mg/L and 18-32 mg/L of each pharmaceutical for NF-90 and BW-30 membranes, respectively), when an initial stream of six pharmaceuticals was feeding to the membrane system (10 mg/L of each pharmaceutical). The abatement of concentrated pharmaceuticals of the rejected stream was evaluated by means of heterogeneous photocatalytic oxidation using TiO2 and Fe2O3/SBA-15 in presence of hydrogen peroxide as photo-Fenton system. Both photocatalytic treatments showed remarkable removals of pharmaceutical compounds, achieving values between 80 and 100 %. The nicotine was the most refractory pollutant of all the studied pharmaceuticals. Photo-Fenton treatment seems to be more effective than TiO2 photocatalysis, as high mineralization degree and increased nicotine removal were attested. This work can be considered an interesting approach of coupling membrane separation and heterogeneous photocatalytic technologies for the successful abatement of pharmaceutical compounds in effluents of wastewater treatment plants.Tecnología Química y AmbientalElsevier201320132013info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10115/11836reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlosinstname:Universidad Rey Juan CarlosInglésAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:burjcdigital.urjc.es:10115/118362026-06-24T12:48:17Z |
| dc.title.none.fl_str_mv |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants |
| title |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants |
| spellingShingle |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants Martínez, F. Medio Ambiente Pharmaceutical Pollutants Nanofiltration Reverse Osmosis Photocatalysis Photo-Fenton 2391 Química Ambiental |
| title_short |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants |
| title_full |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants |
| title_fullStr |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants |
| title_full_unstemmed |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants |
| title_sort |
Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants |
| dc.creator.none.fl_str_mv |
Martínez, F. López-Muñoz, M.J. Aguado, J. Melero, J.A. Arsuaga, J. Sotto, A. Molina, R. Segura, Y. Pariente, M.I. Revilla, A. Cerro, L. Carenas, G. |
| author |
Martínez, F. |
| author_facet |
Martínez, F. López-Muñoz, M.J. Aguado, J. Melero, J.A. Arsuaga, J. Sotto, A. Molina, R. Segura, Y. Pariente, M.I. Revilla, A. Cerro, L. Carenas, G. |
| author_role |
author |
| author2 |
López-Muñoz, M.J. Aguado, J. Melero, J.A. Arsuaga, J. Sotto, A. Molina, R. Segura, Y. Pariente, M.I. Revilla, A. Cerro, L. Carenas, G. |
| author2_role |
author author author author author author author author author author author |
| dc.subject.none.fl_str_mv |
Medio Ambiente Pharmaceutical Pollutants Nanofiltration Reverse Osmosis Photocatalysis Photo-Fenton 2391 Química Ambiental |
| topic |
Medio Ambiente Pharmaceutical Pollutants Nanofiltration Reverse Osmosis Photocatalysis Photo-Fenton 2391 Química Ambiental |
| description |
Línea Investigación: Línea 1. Procesos de depuración de aguas residuales |
| publishDate |
2013 |
| dc.date.none.fl_str_mv |
2013 2013 2013 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10115/11836 |
| url |
http://hdl.handle.net/10115/11836 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.rights.none.fl_str_mv |
Atribución-NoComercial-SinDerivadas 3.0 España http://creativecommons.org/licenses/by-nc-nd/3.0/es/ info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
Atribución-NoComercial-SinDerivadas 3.0 España http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
| dc.source.none.fl_str_mv |
reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos instname:Universidad Rey Juan Carlos |
| instname_str |
Universidad Rey Juan Carlos |
| reponame_str |
BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos |
| collection |
BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos |
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| repository.mail.fl_str_mv |
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1869406119106969600 |
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15,811543 |