Isoreticular Contraction of Metal–Organic Frameworks Induced by Cleavage of Covalent Bonds [Dataset]

46 pages. -- Section S1. General Methods and Materials. -- S1.1 Chemicals and reagents. -- S1.2 Instruments. -- Section S2. Synthetic Procedures. -- S2.1 Synthesis of 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB). -- S2.2 Synthesis of (In)BCN-20B. -- S2.3 Synthesis of (Sc)BCN-20C. -- Sect...

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Detalles Bibliográficos
Autores: Yang, Yunhui, Fernández-Seriñán, Pilar, Imaz, Inhar, Gándara Barragán, Felipe, Handke, Marcel, Ortín-Rubio, Borja, Juanhuix, Judith, Maspoch, Daniel
Tipo de recurso: conjunto de datos
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/341336
Acceso en línea:http://hdl.handle.net/10261/341336
Access Level:acceso abierto
Palabra clave:Various dynamic chemical
Isoreticular contracted mofs
Replaced without destroying
Noncleavable organic linkers
Additional organic linkers
Contraction involves breaking
Cleavable linkers
Subsequent breaking
Isoreticular contraction
Underlying nets
Structural behavior
Reticular materials
Retained throughout
Ray diffraction
Quantitatively broke
Key concept
Inorganic moieties
Include cleavable
Entire transformation
Crystal x
Crystal character
Covalent bonds
Covalent bond
Coordination bond
Descripción
Sumario:46 pages. -- Section S1. General Methods and Materials. -- S1.1 Chemicals and reagents. -- S1.2 Instruments. -- Section S2. Synthetic Procedures. -- S2.1 Synthesis of 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB). -- S2.2 Synthesis of (In)BCN-20B. -- S2.3 Synthesis of (Sc)BCN-20C. -- Section S3. (In)BCN-20B. -- Section S4. (In)BCN-20B’. -- Section S5. (In)BCN-20A. -- Section S6. Structural Evolution from (Sc)BCN-20C to (Sc)BCN-20A. -- References.

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