Superhydrophobic 304 Stainless Steel Mesh for the Removal of High-Density Polyethylene Microplastics

Microplastics are a global issue that affects the environment, economy, as well as human health. Herein, we present a superhydrophobic 304 stainless steel mesh obtained by chemical etching followed by a liquid-phase deposition of lauric acid that can be used for microplastic removal. Field emission...

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Detalhes bibliográficos
Autores: Rius Ayra, Oriol, Tahchieva, Alisiya Biserova, Sansa-López, Victor, Llorca i Isern, Núria
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/214308
Acesso em linha:https://hdl.handle.net/2445/214308
Access Level:acceso abierto
Palavra-chave:Polietilè
Microplàstics
Polyethylene
Microplastics
Descrição
Resumo:Microplastics are a global issue that affects the environment, economy, as well as human health. Herein, we present a superhydrophobic 304 stainless steel mesh obtained by chemical etching followed by a liquid-phase deposition of lauric acid that can be used for microplastic removal. Field emission scanning electron microscopy (FE-SEM) and high-resolution X-ray photoelectron spectroscopy (HR-XPS), among other techniques, were used to identify the hierarchical structure and chemical composition of the surface. They revealed that iron laurate decreased the surface free energy. The 304 stainless steel mesh was superhydrophobic (169°) and superoleophilic (0°). Taking advantage of these wetting properties, we showed an innovative use of these superhydrophobic surfaces in the removal of microplastics. Additionally, we analyzed the removal efficiency from a surface and colloidal point of view that allowed us to explain and clarify why microplastics can also be removed by their wetting properties. The loss of a double electrostatic cloud between the microplastics and the predominance of van der Waals interactions in the organic phase promote the removal of these persistent pollutants from water.