Dataset relative to a theoretical study of the deposition of strapped Ni(II)-porphyrin in metal surfaces

This dataset supports the study of the spin transition of Ni(II)-porphyrin complexes deposited on metal supports. The spin transition is accompanied by the coordination change of the metal center, a phenomenon denominated in coordination-induced spin-state switching (CISSS). The dataset contains the...

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Detalles Bibliográficos
Autores: Jiménez Calzado, Carmen, Montenegro-Pohlhammer, Nicolás, Sánchez de Armas, María Rocío
Tipo de recurso: conjunto de datos
Fecha de publicación:2025
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/179149
Acceso en línea:https://hdl.handle.net/11441/179149
https://doi.org/10.12795/11441/179149
Access Level:acceso abierto
Palabra clave:Ni(II)-porphyrin
DFT calculations
STM
Coordination-induced spin transition
Electric-field effects
Transport measurements
dI/dV spectra
VASP calculations
ORCA calculations
ATK transport calculations
Descripción
Sumario:This dataset supports the study of the spin transition of Ni(II)-porphyrin complexes deposited on metal supports. The spin transition is accompanied by the coordination change of the metal center, a phenomenon denominated in coordination-induced spin-state switching (CISSS). The dataset contains the optimized geometries of the deposited molecule and junction, and key input data for VASP, ORCA and Quantum ATK packages.