Se(IV) immobilization onto natural siderite: implications for high-level nuclear waste repositories

Sorption processes of metals and semimetals on siderite are studied because of its potential adequacy for removing contaminants from natural waters and its wide availability, as well as its capacity to reduce the oxidation state of some contaminants such as selenium. In this work, it has been demons...

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Detalles Bibliográficos
Autores: Pavón Regaña, Sandra|||0000-0002-6577-386X, Pablo Ribas, Joan de|||0000-0001-9538-7321
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/355599
Acceso en línea:https://hdl.handle.net/2117/355599
https://dx.doi.org/10.1002/ceat.202000424
Access Level:acceso abierto
Palabra clave:Radioisotopes
Radioactive wastes
Iron oxides
Nuclear waste
Radionuclides
Selenite ion
Sorption
Isòtops radioactius
Residus radioactius
Àrees temàtiques de la UPC::Enginyeria química
Descripción
Sumario:Sorption processes of metals and semimetals on siderite are studied because of its potential adequacy for removing contaminants from natural waters and its wide availability, as well as its capacity to reduce the oxidation state of some contaminants such as selenium. In this work, it has been demonstrated that siderite reduces selenite ions in solution, showing a higher selenium immobilization capacity compared to other iron(III) minerals, which is probably due to both sorption and reduction processes.