Quest for order in chaos: hidden repulsive level statistics in disordered quantum nanoaggregates
The local distribution of exciton levels in disordered cyanine-dye-based molecular nanoaggregates has been elucidated using fluorescence line narrowing spectroscopy. The observation of a Wigner-Dyson-type level spacing distribution provides direct evidence of the existence of level repulsion of stro...
| Autores: | , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2010 |
| País: | España |
| Recursos: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/42783 |
| Acesso em linha: | https://hdl.handle.net/20.500.14352/42783 |
| Access Level: | acceso abierto |
| Palavra-chave: | 538.9 Localized frenkel excitons Low-temperature Rayleigh-scattering Optical-properties Nanoscale systems Energy Spectroscopy Relaxation Proteins Insights Física de materiales Física del estado sólido 2211 Física del Estado Sólido |
| Resumo: | The local distribution of exciton levels in disordered cyanine-dye-based molecular nanoaggregates has been elucidated using fluorescence line narrowing spectroscopy. The observation of a Wigner-Dyson-type level spacing distribution provides direct evidence of the existence of level repulsion of strongly overlapping states in the molecular wires, which is important for the understanding of the level statistics, and therefore the functional properties, of a large variety of nanoconfined systems. |
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