Radical Cyclization of Trichloroacetamides: Synthesis of Lactams

Trichloroacetamides can act as radical precursors to synthesize nitrogen-containing heterocycles in a variety of processes, mainly involving atom transfer radical cyclizations (ATRC), mediated by Cu(I) or Ru(II) catalysts, and the hydride reductive method, employing either Bu3SnH or (Me3Si)3SiH, or...

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Detalles Bibliográficos
Autores: Coussanes, Guilhem, Vila, X., Diaba, Faïza, Bonjoch i Sesé, Josep
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/119757
Acceso en línea:https://hdl.handle.net/2445/119757
Access Level:acceso abierto
Palabra clave:Lactames
Hidrurs
Lactams
Hydrides
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spelling Radical Cyclization of Trichloroacetamides: Synthesis of LactamsCoussanes, GuilhemVila, X.Diaba, FaïzaBonjoch i Sesé, JosepLactamesHidrursLactamsHydridesTrichloroacetamides can act as radical precursors to synthesize nitrogen-containing heterocycles in a variety of processes, mainly involving atom transfer radical cyclizations (ATRC), mediated by Cu(I) or Ru(II) catalysts, and the hydride reductive method, employing either Bu3SnH or (Me3Si)3SiH, or recently NaBH3CN. Additionally, amine-mediated single-electron transfer cyclizations, as well as radical processes promoted by Ni, Fe, Mn, Ti, and Ag, have been developed.Georg Thieme Verlag Stuttgart · New York2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://hdl.handle.net/2445/119757Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésReproducció del document publicat a: https://doi.org/10.1055/s-0036-1588383Synthesis, 2017, vol. 49, num. 07, p. 1481-1499https://doi.org/10.1055/s-0036-1588383cc-by-nc-nd (c) Coussanes, G. et al., 2017http://creativecommons.org/licenses/by-nc-nd/3.0/esinfo:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1197572026-05-27T06:46:51Z
dc.title.none.fl_str_mv Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
title Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
spellingShingle Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
Coussanes, Guilhem
Lactames
Hidrurs
Lactams
Hydrides
title_short Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
title_full Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
title_fullStr Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
title_full_unstemmed Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
title_sort Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
dc.creator.none.fl_str_mv Coussanes, Guilhem
Vila, X.
Diaba, Faïza
Bonjoch i Sesé, Josep
author Coussanes, Guilhem
author_facet Coussanes, Guilhem
Vila, X.
Diaba, Faïza
Bonjoch i Sesé, Josep
author_role author
author2 Vila, X.
Diaba, Faïza
Bonjoch i Sesé, Josep
author2_role author
author
author
dc.subject.none.fl_str_mv Lactames
Hidrurs
Lactams
Hydrides
topic Lactames
Hidrurs
Lactams
Hydrides
description Trichloroacetamides can act as radical precursors to synthesize nitrogen-containing heterocycles in a variety of processes, mainly involving atom transfer radical cyclizations (ATRC), mediated by Cu(I) or Ru(II) catalysts, and the hydride reductive method, employing either Bu3SnH or (Me3Si)3SiH, or recently NaBH3CN. Additionally, amine-mediated single-electron transfer cyclizations, as well as radical processes promoted by Ni, Fe, Mn, Ti, and Ag, have been developed.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/119757
url https://hdl.handle.net/2445/119757
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1055/s-0036-1588383
Synthesis, 2017, vol. 49, num. 07, p. 1481-1499
https://doi.org/10.1055/s-0036-1588383
dc.rights.none.fl_str_mv cc-by-nc-nd (c) Coussanes, G. et al., 2017
http://creativecommons.org/licenses/by-nc-nd/3.0/es
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by-nc-nd (c) Coussanes, G. et al., 2017
http://creativecommons.org/licenses/by-nc-nd/3.0/es
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Georg Thieme Verlag Stuttgart · New York
publisher.none.fl_str_mv Georg Thieme Verlag Stuttgart · New York
dc.source.none.fl_str_mv Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301629

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