Electrochemical Conversion of 5-Hydroxymethylfurfural to 2,5-Furandicarboxaldehyde Using Mn(III)–Schiff Base Catalysts
2,5-furandicarboxaldehyde (DFF) is one of the most promising biomass-based building blocks for the synthesis of biobased polymers. DFF can be obtained from 5-hydroxymethylfurfural (HMF), a fructose derivate, and it is a key molecule in the sequence of reactions of furan chemistry to develop biobased...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | Universidad de Santiago de Compostela (USC) |
| Repositorio: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela |
| Idioma: | inglés |
| OAI Identifier: | oai:minerva.usc.gal:10347/45770 |
| Acceso en línea: | https://hdl.handle.net/10347/45770 |
| Access Level: | acceso abierto |
| Palabra clave: | 2,5-furandicarboxaldehyde 5-hydroxymethylfurfural Electrocatalyst Manganese Oxidation Schiff base |
| Sumario: | 2,5-furandicarboxaldehyde (DFF) is one of the most promising biomass-based building blocks for the synthesis of biobased polymers. DFF can be obtained from 5-hydroxymethylfurfural (HMF), a fructose derivate, and it is a key molecule in the sequence of reactions of furan chemistry to develop biobased plastics. In this frame, four manganese(III)–Schiff base complexes 1–4 have been obtained. The general formula for the complexes, MnLn(OCN)(H2O/CH3OH)m (Ln being the Schiff base ligands L1–L4, formed as the result of the condensation of different substituted hydroxybenzaldehydes with diverse diamines, and m = 1–3), has been confirmed by characterization through different analytical and spectroscopic techniques. X-ray crystallographic studies for 1 and 2 showed tetragonally distorted octahedral structures, where the Schiff base was placed in the equatorial coordination positions of the Mn(III) ion. Complexes 1 and 2 behaved as efficient catalysts in the oxidation of HMF to DFF in an electrolytic reaction at pH 8.5, with phosphate buffer at room temperature, with conversion rates of 70–80%. On the other hand, complexes 3 and 4, where the axial position was sterically less accessible, yielded only an 11% conversion of HMF to DFF. The results indicate that a correct selection of metal complexes allows the development of a new efficient way to obtain DFF. |
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