Extractability of Low Molecular Mass Flavanols and Flavonols from Red Grape Skins. Relationship to Cell Wall Composition at Different Ripeness Stages

[EN] Flavonol and flavan-3-ol extractabilities from red grape skins were evaluated in Tempranillo grapes harvested at different ripeness stages and with different soluble solid contents within each stage. Flavan-3-ol extractability is related to ripeness stage and also to cell wall composition, main...

Descripción completa

Detalles Bibliográficos
Autores: Quijada Morín, Natalia, Hernández Hierro, José Miguel, Rivas Gonzalo, Julián C., Escribano Bailón, María Teresa
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:España
Institución:Universidad de Salamanca (USAL)
Repositorio:GREDOS. Repositorio Institucional de la Universidad de Salamanca
OAI Identifier:oai:gredos.usal.es:10366/145487
Acceso en línea:http://hdl.handle.net/10366/145487
Access Level:acceso abierto
Palabra clave:Grape skins
Flavanol extractability
Cell wall
Flavan-3-ol extractability
2302 Bioquímica
Descripción
Sumario:[EN] Flavonol and flavan-3-ol extractabilities from red grape skins were evaluated in Tempranillo grapes harvested at different ripeness stages and with different soluble solid contents within each stage. Flavan-3-ol extractability is related to ripeness stage and also to cell wall composition, mainly to arabinogalactans (AG), mannans, rhamnogalacturonans-I (RG-I), homogalacturonans (HG), xyloglucans (XG), and total polysaccharides content, which are negatively correlated to flavan-3-ol extractability, whereas soluble solid content did not exert any influence on their extraction. Moreover, procyanidin extraction is more strongly related to cell wall composition than prodelphinidin extraction. Flavonol extractability was not influenced by insoluble material contents; although some cell wall components presented a relationship with flavonol extractability, the presence of AG and mannans would decrease total flavonol extractability, whereas protein is positively related to total and major flavonol compounds (i.e., quercetin and myricetin derivatives). The different behaviors observed between those two groups of polyphenol compounds could be due to different tissue and cellular location.