Mineralogical Characterization of Slags from the Oiola Site (Biscay, Spain) to Assess the Development in Bloomery Iron Smelting Technology from the Roman Period to the Middle Ages

The Oiola archeological site, located in the mining complex of La Arboleda (Biscay, North Spain)was an important iron smelting center from the Roman Period to the Middle Ages and even in more current times (19th–20th centuries). Tap-slags and some plano-convex slags were identified as smelting slags...

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Detalles Bibliográficos
Autores: Portillo Blanco, Haizea, Zuluaga, María Cruz, Ortega, Luis Ángel, Alonso Olazabal, Ainhoa, Cepeda Ocampo, Juan José|||0000-0002-6643-9142, Martínez Salcedo, Ana
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad de Cantabria (UC)
Repositorio:UCrea Repositorio Abierto de la Universidad de Cantabria
Idioma:inglés
OAI Identifier:oai:repositorio.unican.es:10902/18545
Acceso en línea:http://hdl.handle.net/10902/18545
Access Level:acceso abierto
Palabra clave:Smelting slags
Archaeological slags
Furnace operating conditions
Roman Period
Middle Age
North Spain
Descripción
Sumario:The Oiola archeological site, located in the mining complex of La Arboleda (Biscay, North Spain)was an important iron smelting center from the Roman Period to the Middle Ages and even in more current times (19th–20th centuries). Tap-slags and some plano-convex slags were identified as smelting slags. Samples were analyzed by optical microscopy, X-ray powder diffraction, scanning electron microscopy coupled with electron-dispersive spectroscopy and Raman microspectroscopy to perform a mineralogical and textural characterization. Additionally, thermogravimetric and thermodiffraction analyses were carried out to determine furnace operating temperatures. The mineral assemblage reflects furnace temperatures and cooling rates and the addition of quartz as the main flux to decrease the melting temperature of the iron ore. The comparison of slags from the Roman Period and the Middle Age reveals changes in the pyrometallurgical process through time.